3,3′-Dimethylbenzidine
CAS 119-93-7
EC 204-358-0
Formula C14H16N2
MW 212.29 g/mol
Amines Personal Care & CosmeticsTextile, Leather & PaperPlastics & PolymersPrinting & Packaging Cross-linking & Curing
Description
3,3'-Dimethylbenzidine (CAS 119-93-7, EC 204-358-0) is an aromatic diamine also known as o-Tolidine, Tolidine, or 2-Tolidine, with molecular formula C14H16N2. It belongs to the benzidine family of amines and serves as a chemical intermediate rather than a finished product.
In textile and leather dyeing, o-Tolidine acts as a diazo component that couples with other aromatic compounds to produce azo dyes with strong fiber affinity. In polymer and elastomer manufacturing, its two primary amine groups react with isocyanates or epoxies to form cross-linked networks, contributing to improved mechanical properties. It also functions as a precursor in printing ink colorant synthesis.
This material is supplied as a powder or wet cake and is subject to REACH regulation, with classification as a Category 1A carcinogen requiring strict handling controls. Procurement teams should confirm SDS documentation and confirm compliance with applicable EU chemical regulations before ordering.
In textile and leather dyeing, o-Tolidine acts as a diazo component that couples with other aromatic compounds to produce azo dyes with strong fiber affinity. In polymer and elastomer manufacturing, its two primary amine groups react with isocyanates or epoxies to form cross-linked networks, contributing to improved mechanical properties. It also functions as a precursor in printing ink colorant synthesis.
This material is supplied as a powder or wet cake and is subject to REACH regulation, with classification as a Category 1A carcinogen requiring strict handling controls. Procurement teams should confirm SDS documentation and confirm compliance with applicable EU chemical regulations before ordering.
Physical Properties
| Melting Point | 129-131 °C |
| Boiling Point | 300 °C |
| Density | 1.234 g/cm³ |
| Flash Point | 244 °C |
| Appearance | o-Tolidine is a white to reddish crystal or powder. Darkens on exposure to air. Often used in paste or wet cake form. Used as a basis for many dyes. |
| Color | light brown |
| Form | powder (may contain lumps) |
| Water Solubility | Slightly soluble in water. |
| Refractive Index | n 20/D 1.341 |
Safety & Handling (Learn More)
Danger GHS07 GHS08 GHS09
H
H302H341H350H351H372H373H401H411
P
P203P260P264P270P273P280P318P319P330P391P405P501P301+P317
Trade & Regulatory
| HS Code | 29215900 |
| UN Number | 3082 |
| ADR Class | 9 |
| Packing Group | III |
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
| WGK (Germany) | 3 |
Other Names
o-Tolidine4-(4-amino-3-methylphenyl)-2-methylaniline3,3'-tolidinediaminoditolylDMBTolidine2-Tolidino-Tolidin
Related Products
Raw Materials
Need a chemical? Get a quote within 24 hours.