SoleChem

3,3′-Dimethylbenzidine

CAS 119-93-7
EC 204-358-0
Formula C14H16N2
MW 212.29 g/mol
Amines Personal Care & CosmeticsTextile, Leather & PaperPlastics & PolymersPrinting & Packaging Cross-linking & Curing

Description

3,3'-Dimethylbenzidine (CAS 119-93-7, EC 204-358-0) is an aromatic diamine also known as o-Tolidine, Tolidine, or 2-Tolidine, with molecular formula C14H16N2. It belongs to the benzidine family of amines and serves as a chemical intermediate rather than a finished product.

In textile and leather dyeing, o-Tolidine acts as a diazo component that couples with other aromatic compounds to produce azo dyes with strong fiber affinity. In polymer and elastomer manufacturing, its two primary amine groups react with isocyanates or epoxies to form cross-linked networks, contributing to improved mechanical properties. It also functions as a precursor in printing ink colorant synthesis.

This material is supplied as a powder or wet cake and is subject to REACH regulation, with classification as a Category 1A carcinogen requiring strict handling controls. Procurement teams should confirm SDS documentation and confirm compliance with applicable EU chemical regulations before ordering.

Physical Properties

Melting Point 129-131 °C
Boiling Point 300 °C
Density 1.234 g/cm³
Flash Point 244 °C
Appearance o-Tolidine is a white to reddish crystal or powder. Darkens on exposure to air. Often used in paste or wet cake form. Used as a basis for many dyes.
Color light brown
Form powder (may contain lumps)
Water Solubility Slightly soluble in water.
Refractive Index n 20/D 1.341

Safety & Handling (Learn More)

Danger GHS07 GHS08 GHS09
H
H302H341H350H351H372H373H401H411
P
P203P260P264P270P273P280P318P319P330P391P405P501P301+P317

Trade & Regulatory

HS Code 29215900
UN Number 3082
ADR Class 9
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 3

Other Names

o-Tolidine4-(4-amino-3-methylphenyl)-2-methylaniline3,3'-tolidinediaminoditolylDMBTolidine2-Tolidino-Tolidin

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