SoleChem

Azodicarbonamide

CAS 123-77-3
EC 204-650-8
Formula C2H4N4O2
MW 116.08 g/mol
Catalysts & Catalyst Precursors Plastics & PolymersFood & NutritionTextile, Leather & PaperRubber & TirePersonal Care & Cosmetics CatalysisFoam ControlPreservation & BiocidepH Regulation & Buffering

Description

Azodicarbonamide (CAS 123-77-3) is a synthetic chemical blowing agent and dough conditioner, commercially available under trade names including Celogen AZ and AZOFOAM E, and also referred to as azodiformamide or azodicarbamide. It carries no E-code designation in the EU, where its use as a food additive is not permitted.

In polymer and rubber processing, azodicarbonamide decomposes at temperatures between 195–215°C to release nitrogen, carbon dioxide, and carbon monoxide, generating a uniform closed-cell foam structure in PVC, polyolefins, and rubber compounds. In textile and flour treatment applications, it acts as an oxidising agent, modifying protein structures to improve dough rheology or fibre processing characteristics.

Azodicarbonamide is supplied as an orange crystalline powder in standard and fine-particle grades, with decomposition temperature variants available to suit specific processing windows. It falls under REACH registration requirements within the EU and is classified under HS code 29270000. Packaging is typically available in 25 kg bags.

Physical Properties

Melting Point 225 °C (decomp)
Boiling Point 217.08°C (rough estimate)
Density 1.65 g/cm³ @ Temp: 20 °C
Flash Point 225 °C
Appearance orange crystalline powder
Color Yellow to orange-red crystalline powder
Odor odorless
Form Solid
Water Solubility SOLUBLE IN HOT WATER
Vapor Pressure 0Pa at 25℃
Refractive Index 1.4164 (estimate)
pH 7 ( in H2O, neutral)
Log P -1.148 (est)

Safety & Handling (Learn More)

Danger GHS08 GHS02 GHS07
H
H228H317H334H402H412
P
P210P233P240P241P260P261P271P272P273P280P284P321P403P501P302+P352P304+P340P333+P317P342+P316P362+P364P370+P378

Trade & Regulatory

HS Code 29270000
UN Number 3242
ADR Class 4.1
Packing Group II
Storage Class 4.1A - Other explosive hazardous materials
WGK (Germany) 1

Other Names

(E)-carbamoyliminoureaADCAazo(bis)formamide(E/Z)-azodicarbonamideAZOFOAM ECelogen AZΔ1,1′-BiureaAzodiformamideAzodicarbamide

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