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Borane-triethylamine complex

CAS 1722-26-5
EC 217-022-3
Formula C6H18BN
MW 115.02 g/mol
Organometallic Compounds Pharmaceuticals & HealthcareBiotechnology & Life SciencesPlastics & PolymersElectronics CatalysisPolymerization Initiation

Description

Borane-triethylamine complex (CAS 1722-26-5, EC 217-022-3) is a stabilised borane reagent commercially known as TEAB or triethylamine borane, with the abbreviated formula (C2H5)3NBH3. It carries no assigned E-code. The triethylamine ligand moderates the reactivity of the borane, making it safer to handle than free borane gas.

In pharmaceutical synthesis, TEAB functions as a selective reducing agent for imines and carbonyl compounds under controlled conditions, offering chemists a milder alternative to lithium aluminium hydride. In polymer chemistry, it serves as a radical initiator for polymerisation reactions, generating boron-centred radicals that activate monomer chains at ambient or low temperatures.

TEAB is supplied under REACH compliance and is available in standard laboratory and bulk quantities as a neat liquid. Procurement teams should confirm purity grade and inhibitor content with the supplier prior to ordering, as specifications vary by intended application.

Physical Properties

Melting Point -4 °C
Boiling Point 97 °C @ Press: 12 Torr
Density 0.78 g/cm³
Flash Point 20 °F
Appearance clear colourless liquid
Color Colorless to pale yellow
Form Liquid
Water Solubility MAY DECOMPOSE
Refractive Index n 20/D 1.444

Safety & Handling (Learn More)

Danger GHS02 GHS05 GHS06 GHS07 GHS09
H
H225H226H301H302H311H312H314H318H331H332H411
P
P210P233P240P241P242P243P260P261P262P264P270P271P273P280P316P317P321P330P363P391P405P501P264+P265P301+P316P301+P317P302+P352P304+P340P361+P364P362+P364P370+P378P403+P233P403+P235P301+P330+P331P302+P361+P354P303+P361+P353P305+P354+P338

Trade & Regulatory

HS Code 29299090
UN Number 2924
ADR Class 3
Packing Group II
Storage Class 3 - Flammable liquids
WGK (Germany) 3

Other Names

Triethylamine boraneBorane triethylamine complexTEAB(C2H5)3NBH3N-Triethyl borazaneBORANE-TRIETHYLAMINEBorazane, N,N,N-triethyl-

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