SoleChem

Calomel

CAS 10112-91-1
EC 233-307-5
Formula Cl2Hg2
MW 472.09 g/mol
Salts & Minerals Pharmaceuticals & HealthcareElectronics Catalysis

Description

Calomel (CAS 10112-91-1, EC 233-307-5, formula Cl2Hg2) is a mercurous chloride compound, also known by the trade names Calotab, Calogreen, and Cyclosan, and abbreviated in technical literature as Hg2Cl2 or ClHgHgCl. It carries no assigned E-code and is classified within the salts and minerals category.

In electronics, calomel serves as a reference electrode material in electrochemical cells, where its stable redox potential provides a reproducible voltage baseline for precise measurements. In pharmaceutical research and catalysis, it functions as a mercury-based catalyst precursor, facilitating specific reaction pathways where controlled mercury ion release is required under defined conditions.

Calomel is supplied as a crystalline powder grade suitable for laboratory and industrial use, subject to REACH regulation (EC 1907/2006) given its mercury content, which also triggers classification under CLP and relevant RoHS considerations for electronic applications. Procurement teams should confirm current authorization status prior to ordering.

Physical Properties

Melting Point 400 °C (sublm)
Boiling Point 384 °C
Density 7.15 g/cm³
Appearance White, rhombic crystals or crystalline powder; odorless. Stable in air but darkens on exposure to light.decomposed by alkalies. Insoluble in water, ether, alcohol, and cold dilute acids.
Color White
Odor Odorless
Form powder
Water Solubility Soluble in (0.002g/L )water.
Vapor Pressure 1.7 mm Hg at 236 °C

Safety & Handling (Learn More)

Danger GHS07 GHS09 GHS06 GHS08
H
H301H302H312H315H317H319H320H335H341H361H370H372H400H410
P
P203P260P261P264P270P271P272P273P280P317P318P319P321P330P391P405P501P264+P265P301+P316P301+P317P302+P352P304+P340P308+P316P332+P317P333+P317P337+P317P362+P364P403+P233P305+P351+P338

Trade & Regulatory

UN Number 2811
ADR Class 6.1
Packing Group III
WGK (Germany) 3

Other Names

Mercury(I) ChloridechloromercuryHg2Cl2ClHgHgClmercurous chlorideCalotab

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