SoleChem

Chromic acid

CAS 7738-94-5
EC 231-801-5
Formula CrH2O4
MW 118.01 g/mol
Oxidizers & Peroxides Mining & MetalsTextile, Leather & Paper Bleaching & WhiteningSurface Modification & WettingCorrosion Inhibition

Description

Chromic acid (CAS 7738-94-5, EC 231-801-5, formula CrH2O4) is an inorganic chromium(VI) compound also referred to as H2CrO4 or chromic(VI) acid. It carries no assigned E-code and is distinct from chromium trioxide, though the two are closely related in industrial practice.

In metal finishing and mining operations, chromic acid acts as an oxidising agent that etches and passivates metal surfaces, creating a corrosion-resistant oxide layer through controlled electrochemical reaction. In textile and leather processing, it functions as a bleaching and surface-modification agent, breaking down organic chromophores and altering fibre structure to improve dye uptake and uniformity.

Chromic acid is subject to REACH regulation as a substance of very high concern (SVHC) under Annex XIV, requiring authorisation for use within the EU. It is available in technical and industrial grades, supplied as dark crystalline flakes or concentrated aqueous solution, with packaging formats typically including UN-approved drums and intermediate bulk containers.

Physical Properties

Melting Point 196 °C
Boiling Point 250 °C (decomposes)
Density 1.67-2.82 g/cm³
Appearance Chromic acid is a dark purplish-red odorless flakes or crystalline powder
Color Clear, orange
Odor Odorless
Form Liquid
Water Solubility HIGHLY Soluble
pH 3.03(1 mM solution);2.33(10 mM solution);2.06(100 mM solution)

Safety & Handling (Learn More)

Danger GHS03 GHS05 GHS06 GHS07 GHS08 GHS09
H
H271H300H301H310H311H312H314H317H318H330H334H340H341H350H361H372H400H410
P
P203P210P220P233P260P261P262P264P270P271P272P273P280P283P284P316P317P318P319P320P321P330P363P391P403P405P420P501P264+P265P301+P316P302+P352P304+P340P306+P360P333+P317P342+P316P361+P364P362+P364P370+P378P403+P233P301+P330+P331P302+P361+P354P305+P354+P338P371+P380+P375

Trade & Regulatory

UN Number 1463

Other Names

dihydroxy(dioxo)chromiumH2CrO4[CrO2(OH)2]Cromic acidChromic(VI) acidChromic acid (H2CrO4)Chromic acid USP/EP/BP

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