SoleChem

Crotonic acid

CAS 3724-65-0
EC 223-077-4
Formula C4H6O2
MW 86.09 g/mol
Organic Acids Food & NutritionPlastics & PolymersAgriculture & FeedPharmaceuticals & Healthcare Flavoring & AcidulantPolymerization Initiation

Description

Crotonic acid (CAS 3724-65-0, EC 223-077-4, C4H6O2), also known as 2-butenoic acid, alpha-butenoic acid, and FEMA 3908, is a short-chain unsaturated organic acid. It does not carry an E-code designation and is distinct from its geometric isomer, isocrotonic acid.

In polymer chemistry, crotonic acid functions as a reactive monomer and chain-transfer agent, incorporating carboxylic functionality into vinyl and acrylic copolymer systems to modify adhesion and film-forming properties. In food and flavor applications, it serves as a flavoring agent under FEMA 3908, contributing characteristic acidic and pungent notes at controlled concentrations.

Crotonic acid is available in solid technical and food-grade forms, with supply compliant with REACH registration requirements for the European market. FCC-grade material is available for flavor applications. It may also be sourced as a molten liquid for bulk industrial handling.

Physical Properties

Melting Point 72 °C
Boiling Point 185 °C
Density 1.018 g/cm³ @ Temp: 15 °C
Flash Point 190 °F
Appearance Crotonic acid is a white or colorless, crystalline solid with a pungent odor. May be transported as a molten liquid.
Odor at 0.10 % in propylene glycol. roasted burnt
Water Solubility soluble
Vapor Pressure 0.19 mm Hg ( 20 °C)
Refractive Index 1.4210 (estimate)
Log P 0.720

Safety & Handling (Learn More)

Danger GHS05 GHS07 GHS06
H
H302H311H312H314H315H318H319H335
P
P260P261P262P264P270P271P280P316P317P319P321P330P363P405P501P264+P265P301+P317P302+P352P304+P340P332+P317P337+P317P361+P364P362+P364P403+P233P301+P330+P331P302+P361+P354P305+P351+P338P305+P354+P338

Trade & Regulatory

UN Number 2823
ADR Class 8
Packing Group III
Storage Class 8A - Combustible corrosive hazardous materials
WGK (Germany) 3

Other Names

(E)-but-2-enoic acidCTA2-butenic acid2-butenoic acidAlpha-Butenoic AcidBUTENOIC ACIDα-Butenoic acid

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