Ethyl methyl ketone peroxide
CAS 1338-23-4
EC 215-661-2
Formula Unspecified
MW 178.23 g/mol
Oxidizers & Peroxides Plastics & PolymersRubber & Tire Polymerization InitiationCross-linking & Curing
Description
Ethyl methyl ketone peroxide (MEKP, CAS 1338-23-4) is an organic peroxide supplied under trade names including Ketonox, Permek N, and Butanox. It is a reactive oxidizing agent classified under EC 215-661-2 and handled under strict ADR transport regulations due to its peroxide content.
In unsaturated polyester resin systems, MEKP acts as a free-radical initiator, decomposing in the presence of a cobalt accelerator to generate radicals that trigger cross-linking and cure the resin at ambient temperature. It is also used to initiate polymerization in gel coats and fiberglass-reinforced composites within the plastics and rubber processing industries.
MEKP is available in stabilized liquid formulations at varying active oxygen concentrations, typically diluted in plasticizers to reduce hazard classification. Supply is subject to REACH registration requirements, and handling must comply with EU Regulation 528/2012 where applicable. Packaging is typically in UN-approved containers suited for organic peroxide transport categories.
In unsaturated polyester resin systems, MEKP acts as a free-radical initiator, decomposing in the presence of a cobalt accelerator to generate radicals that trigger cross-linking and cure the resin at ambient temperature. It is also used to initiate polymerization in gel coats and fiberglass-reinforced composites within the plastics and rubber processing industries.
MEKP is available in stabilized liquid formulations at varying active oxygen concentrations, typically diluted in plasticizers to reduce hazard classification. Supply is subject to REACH registration requirements, and handling must comply with EU Regulation 528/2012 where applicable. Packaging is typically in UN-approved containers suited for organic peroxide transport categories.
Physical Properties
| Melting Point | <25 °C |
| Boiling Point | 19 °C |
| Density | 1.18 g/cm³ |
| Flash Point | 190 °F |
| Appearance | MEKP, an organic peroxide, is a colorless liquid. |
| Form | Liquid |
| Water Solubility | 0.1-0.5 g/100 mL at 22 ºC |
| Vapor Pressure | 0.644-73.6Pa at 25℃ |
| Refractive Index | n 20/D 1.455 |
| Log P | 0.3 at 25℃ |
Safety & Handling (Learn More)
Danger GHS02 GHS05 GHS07 GHS01 GHS06 GHS08
H
H227H241H242H302H312H313H314H315H318H330H332H335H336H341H370H373H401H302+H332
P
P203P210P234P235P240P260P261P264P270P271P273P280P284P316P317P318P319P320P321P330P363P378P403P405P410P411P420P501P264+P265P301+P317P302+P317P302+P352P304+P340P308+P316P332+P317P362+P364P370+P378P403+P233P301+P330+P331P302+P361+P354P305+P354+P338P370+P380+P375
Trade & Regulatory
| UN Number | 3105 |
| ADR Class | 5.2 |
| Storage Class | 5.2 - Organic peroxides and self-reacting hazardous materials |
| WGK (Germany) | 1 |
Other Names
Methyl Ethyl Ketone Peroxide2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butaneMEKPMEK peroxide2-butanone peroxideKetonoxPermek N
Related Products
Raw Materials
Need a chemical? Get a quote within 24 hours.