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Hexafluoroisopropyl acrylate

CAS 2160-89-6
EC 218-479-1
Formula C6H4F6O2
MW 222.09 g/mol
Monomers & Building Blocks Plastics & PolymersElectronicsAerospace & Defense Polymerization InitiationSurface Modification & Wetting

Description

Hexafluoroisopropyl Acrylate (CAS 2160-89-6, EC 218-479-1) is a fluorinated acrylic monomer commercially known as HFIPA, HFIP-A, and R 7210. It carries no assigned E-code. The hexafluoroisopropyl ester group imparts strong electron-withdrawing character, distinguishing it from standard acrylate monomers.

In fluoropolymer synthesis, HFIPA copolymerizes with other acrylates or vinyl monomers to introduce oleophobic and hydrophobic surface properties into coatings used in aerospace components and printed circuit board encapsulants. The fluorinated side chain lowers surface energy at the polymer interface, reducing adhesion of oils, flux residues, and atmospheric contaminants without requiring post-treatment steps.

Hexafluoroisopropyl Acrylate is supplied as a technical-grade clear liquid and falls under HS code 29161290. It is subject to REACH registration requirements within the EU. Packaging is available in laboratory quantities through to drum volumes; suppliers should be consulted directly for current lot specifications and documentation.

Physical Properties

Boiling Point 84-85 °C @ Press: 760 Torr
Density 1.335 g/cm³ @ Temp: 20 °C
Flash Point 50 °F
Appearance clear colorless liquid
Color Colorless to Almost colorless
Form clear liquid
Water Solubility Insoluble
Vapor Pressure 1.22 psi ( 20 °C)
Refractive Index n 20/D 1.319(lit.)

Safety & Handling (Learn More)

Danger GHS02 GHS07 GHS09
H
H225H315H319H335H411
P
P210P233P240P241P242P243P261P264P271P273P280P319P321P391P405P501P264+P265P302+P352P304+P340P332+P317P337+P317P362+P364P370+P378P403+P233P403+P235P303+P361+P353P305+P351+P338

Trade & Regulatory

HS Code 29161290
UN Number 3272
ADR Class 3
Packing Group II
Storage Class 3 - Flammable liquids
WGK (Germany) 2

Other Names

1,1,1,3,3,3-hexafluoropropan-2-yl prop-2-enoateHFIPAHFIP-AR 7210Perfluoroisopropyl acrylateHEXAFLUORO-2-PROPYL ACRYLATEDiperfluoromethylmethyl acrylate1,1,1,3,3,3-HEXAFLUOROISOPROPYL ACRYLATE

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