Hexamethylenediamine
CAS 124-09-4
EC 204-679-6
Formula C6H16N2
MW 116.2 g/mol
Amines Personal Care & CosmeticsPlastics & PolymersFood & Nutrition Cross-linking & CuringFlavoring & AcidulantpH Regulation & Buffering
Description
Hexamethylenediamine (HMDA), also known as 1,6-hexanediamine or 1,6-diaminohexane, is a difunctional aliphatic diamine with CAS 124-09-4. It carries no E-code designation and is classified under the amines category, with HS code 29212290.
In polymer manufacturing, HMDA reacts with diacids such as adipic acid to form polyamide chains, most notably Nylon-6,6, through condensation polymerization. In personal care formulations, it functions as a crosslinker and pH buffer, building network structures in conditioning systems and stabilizing acidic or alkaline formulations within target ranges.
HMDA is available in food-contact and technical grades, supplied as pellets or flakes. It is subject to REACH registration requirements within the EU. Procurement quantities typically range from drum to bulk tanker formats, and buyers should confirm grade suitability against FCC or internal specification standards prior to ordering.
In polymer manufacturing, HMDA reacts with diacids such as adipic acid to form polyamide chains, most notably Nylon-6,6, through condensation polymerization. In personal care formulations, it functions as a crosslinker and pH buffer, building network structures in conditioning systems and stabilizing acidic or alkaline formulations within target ranges.
HMDA is available in food-contact and technical grades, supplied as pellets or flakes. It is subject to REACH registration requirements within the EU. Procurement quantities typically range from drum to bulk tanker formats, and buyers should confirm grade suitability against FCC or internal specification standards prior to ordering.
Physical Properties
| Melting Point | 42 °C |
| Boiling Point | 205 °C |
| Density | 0.93 g/cm³ |
| Flash Point | 201 °F |
| Appearance | HMDA is a hygroscopic, colorless solid (pellets or flakes). Weak, fishy odor. |
| Color | White, may discolor during storage |
| Odor | pyridine odor |
| Form | Solution |
| Water Solubility | 490 g/L (20 ºC) |
| Vapor Pressure | 0.25 hPa (20 °C) |
| Refractive Index | n 20/D 1.439(lit.) |
| pH | 12.4 (100g/l, H2O, 25℃) |
| Log P | 0.4 at 25℃ |
Safety & Handling (Learn More)
Danger GHS05 GHS07 GHS08
H
H302H312H314H317H318H335H361H370H371H372H373H402H302+H312
P
P203P260P261P264P270P271P272P273P280P316P317P318P319P321P330P363P405P501P264+P265P301+P317P302+P352P304+P340P308+P316P333+P317P362+P364P403+P233P301+P330+P331P302+P361+P354P305+P354+P338
Trade & Regulatory
| HS Code | 29212290 |
| UN Number | 2735 |
| ADR Class | 8 |
| Packing Group | III |
| Storage Class | 8A - Combustible corrosive hazardous materials |
| WGK (Germany) | 3 |
Other Names
hexane-1,6-diamineHEX-NH2V 1HMDAHi PermH2N(CH2)6NH2Hexylenediamine1,6-HEXANEDIAMINE1,6-DIAMINOHEXANE
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Raw Materials
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