SoleChem

Hydrogen fluoride

CAS 7664-39-3
EC 231-634-8
Formula FH
MW 20.01 g/mol
Inorganic Acids Mining & MetalsElectronicsPharmaceuticals & HealthcareWater Treatment Preservation & BiocidepH Regulation & BufferingCleaning & Degreasing

Description

Hydrogen fluoride (CAS 7664-39-3), also known as HF, fluohydric acid, or fluorhydric acid, is a strong inorganic acid produced by reacting fluorite with sulfuric acid. It carries no assigned E-code and is classified under the Inorganic Acids category. No common food-grade abbreviation applies.

In electronics manufacturing, HF etches silicon dioxide layers from semiconductor wafers by selectively dissolving the oxide through fluoride ion attack on Si-O bonds. In mining and metals processing, it dissolves metal oxides and silicate gangue during ore beneficiation and metal surface pickling. Pharmaceutical and water treatment applications exploit its buffering capacity to maintain precise pH ranges in process streams.

This product is supplied as a liquid produced via double sub-boiling quartz distillation, yielding high-purity grades suitable for semiconductor and analytical applications. It falls under REACH regulation and requires strict hazard communication under CLP. HS code 28111100 applies for import and export classification across EU member states.

Physical Properties

Melting Point -83.36 °C
Boiling Point 20 °C
Density 0.991 g/cm³ @ Temp: 19.54 °C
Flash Point 112°C
Appearance colourless gas with a pungent odour
Color max. 10
Odor Acrid, irritating odor
Form Liquid, Double Sub-Boiling Quartz Distillation
Water Solubility soluble
Vapor Pressure 25 mm Hg ( 20 °C)
pH 3.27(1 mM solution);2.65(10 mM solution);2.12(100 mM solution)
Log P 0.1 at 20℃

Safety & Handling (Learn More)

Danger GHS05 GHS06 GHS04 GHS08 GHS07
H
H280H290H300H310H311H314H317H318H330H331H341H370H372H402
P
P203P234P260P261P262P264P270P271P272P273P280P284P316P317P318P319P320P321P330P363P390P405P406P501P264+P265P301+P316P302+P352P304+P340P308+P316P333+P317P361+P364P362+P364P403+P233P410+P403P301+P330+P331P302+P361+P354P305+P354+P338

Trade & Regulatory

HS Code 28111100
UN Number 1790
ADR Class 8
Packing Group II
Storage Class 6.1B - Non-combustible, acute toxic Cat. 1 and 2 very toxic hazardous materials
WGK (Germany) 2

Other Names

fluorane[HF]Antisal 2bFLUOHYDRIC ACIDFluorhydric acidHydrogen flurideHydrofluoric acidAcido fluoridrico

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