Lithium hexafluorophosphate
CAS 21324-40-3
EC 244-334-7
Formula F6P.Li
MW 151.91 g/mol
Salts & Minerals Electronics Preservation & Biocide
Description
Lithium hexafluorophosphate (LiPF6, CAS 21324-40-3) is an inorganic lithium salt composed of a lithium cation paired with a hexafluorophosphate anion. It carries no assigned E-code and is not classified as a food additive. In technical literature it is consistently abbreviated as LiPF6.
In electronics manufacturing, LiPF6 serves as the primary electrolyte salt in lithium-ion battery cells, where it dissociates in organic carbonate solvents to provide the lithium-ion conductivity required for charge and discharge cycles. It is also evaluated in antimicrobial formulations, where the hexafluorophosphate anion disrupts microbial membrane integrity.
LiPF6 is supplied as a white crystalline powder in battery-grade and technical-grade specifications, with purity levels typically at or above 99.9% for electrochemical applications. The substance is registered under REACH and subject to standard handling controls for reactive fluorine-containing compounds. Packaging is available in moisture-sealed containers to prevent hydrolytic degradation.
In electronics manufacturing, LiPF6 serves as the primary electrolyte salt in lithium-ion battery cells, where it dissociates in organic carbonate solvents to provide the lithium-ion conductivity required for charge and discharge cycles. It is also evaluated in antimicrobial formulations, where the hexafluorophosphate anion disrupts microbial membrane integrity.
LiPF6 is supplied as a white crystalline powder in battery-grade and technical-grade specifications, with purity levels typically at or above 99.9% for electrochemical applications. The substance is registered under REACH and subject to standard handling controls for reactive fluorine-containing compounds. Packaging is available in moisture-sealed containers to prevent hydrolytic degradation.
Physical Properties
| Melting Point | 200.00 °C |
| Boiling Point | 90°C |
| Density | 1.5 g/cm³ (solid) |
| Flash Point | 25 °C |
| Appearance | white crystalline powder |
| Color | APHA: <50 |
| Form | Powder |
| Water Solubility | soluble |
Safety & Handling (Learn More)
Danger GHS05 GHS06 GHS07 GHS08
H
H301H302H311H314H318H372
P
P260P262P264P270P280P316P317P319P321P330P363P405P501P264+P265P301+P316P301+P317P302+P352P304+P340P361+P364P301+P330+P331P302+P361+P354P305+P354+P338
Trade & Regulatory
| HS Code | 28269020 |
| UN Number | 3260 |
| ADR Class | 8 |
| Packing Group | I |
| Storage Class | 6.1B - Non-combustible acute toxic Cat. 1 and 2 very toxic hazardous materials |
| WGK (Germany) | 3 |
Other Names
LiPF6LBG 45864LBC 305-01Lithium fluophosphatehexafluoro-phosphate(1-lithiumlithium hexafluorophosphate(1-)
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