SoleChem

Lithium hexafluorophosphate

CAS 21324-40-3
EC 244-334-7
Formula F6P.Li
MW 151.91 g/mol
Salts & Minerals Electronics Preservation & Biocide

Description

Lithium hexafluorophosphate (LiPF6, CAS 21324-40-3) is an inorganic lithium salt composed of a lithium cation paired with a hexafluorophosphate anion. It carries no assigned E-code and is not classified as a food additive. In technical literature it is consistently abbreviated as LiPF6.

In electronics manufacturing, LiPF6 serves as the primary electrolyte salt in lithium-ion battery cells, where it dissociates in organic carbonate solvents to provide the lithium-ion conductivity required for charge and discharge cycles. It is also evaluated in antimicrobial formulations, where the hexafluorophosphate anion disrupts microbial membrane integrity.

LiPF6 is supplied as a white crystalline powder in battery-grade and technical-grade specifications, with purity levels typically at or above 99.9% for electrochemical applications. The substance is registered under REACH and subject to standard handling controls for reactive fluorine-containing compounds. Packaging is available in moisture-sealed containers to prevent hydrolytic degradation.

Physical Properties

Melting Point 200.00 °C
Boiling Point 90°C
Density 1.5 g/cm³ (solid)
Flash Point 25 °C
Appearance white crystalline powder
Color APHA: <50
Form Powder
Water Solubility soluble

Safety & Handling (Learn More)

Danger GHS05 GHS06 GHS07 GHS08
H
H301H302H311H314H318H372
P
P260P262P264P270P280P316P317P319P321P330P363P405P501P264+P265P301+P316P301+P317P302+P352P304+P340P361+P364P301+P330+P331P302+P361+P354P305+P354+P338

Trade & Regulatory

HS Code 28269020
UN Number 3260
ADR Class 8
Packing Group I
Storage Class 6.1B - Non-combustible acute toxic Cat. 1 and 2 very toxic hazardous materials
WGK (Germany) 3

Other Names

LiPF6LBG 45864LBC 305-01Lithium fluophosphatehexafluoro-phosphate(1-lithiumlithium hexafluorophosphate(1-)

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