SoleChem

N-Methylolacrylamide

CAS 924-42-5
EC 213-103-2
Formula C4H7NO2
MW 101.1 g/mol
Monomers & Building Blocks Plastics & PolymersTextile, Leather & PaperPersonal Care & Cosmetics Polymerization InitiationCross-linking & CuringPreservation & BiocideSurface Modification & Wetting

Description

N-Methylolacrylamide (CAS 924-42-5), also known as NMA 60, Monomethylolacrylamide, and N-Methanolacrylamide, is a reactive acrylamide-based monomer carrying both a polymerizable vinyl group and a methylol functional group. It carries no assigned E-code and is handled as a solid under standard storage conditions.

In textile and paper finishing, NMA 60 acts as a cross-linking agent by forming covalent bonds with cellulose hydroxyl groups, improving dimensional stability and wet strength. In polymer systems, its dual functionality allows it to co-polymerize into acrylic networks while simultaneously introducing reactive sites for further cross-linking or surface grafting.

N-Methylolacrylamide is supplied under REACH registration and is subject to classification review given its acrylamide-related structure. It is available in solid form, typically as a stabilized aqueous solution at 60% concentration for industrial use. Procurement teams should confirm SDS compliance and regional restrictions before ordering.

Physical Properties

Melting Point 74.5 °C
Boiling Point 277°C(lit.)
Density 1.082 g/mL at 20 °C
Flash Point 100°C
Color White to Off-White
Form Solid
Water Solubility <0.1 g/100 mL at 20.5 ºC
Vapor Pressure 31 hPa (25 °C)
Refractive Index n 20/D 1.413
pH 6.0-7.0 (H2O, 20°C)
Log P -1.81 at 20℃ and pH7

Safety & Handling (Learn More)

Danger GHS08 GHS06 GHS07
H
H301H302H315H317H319H335H340H350H351H360H361H371H372H373H413
P
P203P260P261P264P270P271P272P273P280P318P319P321P330P405P501P264+P265P301+P316P301+P317P302+P352P304+P340P308+P316P332+P317P333+P317P337+P317P362+P364P403+P233P305+P351+P338

Trade & Regulatory

HS Code 29241990
Storage Class 6.1D - Non-combustible acute toxic Cat.3 toxic hazardous materials or hazardous materials causing chronic effects
WGK (Germany) 3

Other Names

N-(hydroxymethyl)acrylamideN-(hydroxymethyl)-2-propenamideN-(hydroxymethyl)prop-2-enamideNMANMA 60MH 100NCI-C60333MH 100 (amide)METHYLOLACRYLAMIDE

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