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Phosphorus pentasulfide

CAS 1314-80-3
EC 215-242-4
Formula P.S
MW 191.3 g/mol
Inorganic Acids Lubricants & MetalworkingMining & MetalsAgriculture & Feed CatalysisLubrication

Description

Phosphorus pentasulfide (CAS 1314-80-3, EC 215-242-4), also known as P4S10, phosphorus sulfide, and phosphoric sulfide, is an inorganic compound formed by the reaction of phosphorus and sulfur. It carries no assigned E-code and is classified under HS code 28139000 within the inorganic acids category.

In lubricant formulation, phosphorus pentasulfide reacts with alcohols or hydrocarbons to produce zinc dialkyldithiophosphate (ZDDP) and similar antiwear additives, which form protective films on metal surfaces under high-pressure conditions. In mining and mineral processing, it serves as a flotation reagent precursor, and in agrochemical synthesis it acts as a sulfur-transfer agent in the production of organophosphate pesticides.

Phosphorus pentasulfide is supplied as a technical-grade crystalline solid and is subject to REACH registration requirements for European procurement. Packaging typically follows hazardous goods standards given its reactivity with moisture. Buyers should confirm lot-specific documentation and SDS compliance prior to ordering.

Physical Properties

Melting Point 286-290 °C
Boiling Point 513-515 °C
Density 2.062 g/cm³
Appearance Phosphorus pentasulfide is a greenish-gray to yellow, crystalline solid with an odor of rotten eggs. The Odor Threshold is 0.005 ppm
Color Yellow to green
Odor rotten egg odor
Form Powder
Water Solubility reacts
pH 1 (10g/l, H2O, 20℃)

Safety & Handling (Learn More)

Danger GHS02 GHS07 GHS09 GHS05 GHS06 GHS08
H
H228H260H261H301H302H311H313H314H315H318H319H332H335H371H400H301+H331H302+H332
P
P210P223P240P241P260P261P262P264P270P271P273P280P316P317P319P321P330P363P391P405P501P231+P232P264+P265P301+P316P301+P317P302+P317P302+P352P304+P340P308+P316P332+P317P337+P317P361+P364P362+P364P370+P378P402+P404P403+P233P301+P330+P331P302+P335+P334P302+P361+P354P305+P351+P338P305+P354+P338

Trade & Regulatory

HS Code 28139000
UN Number 1340
ADR Class 4.3
Packing Group II
Storage Class 4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK (Germany) 3

Other Names

P4S10sulfur phosphidephosphorus sulfidePhosphoric sulfidePhosphorus persulfidePHOSPHORUS(V) SULFIDEPHOSPHORUS PERSULPHIDE

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