SoleChem

Sodium hydrosulfide

CAS 16721-80-5
EC 240-778-0
Formula HNaS
MW 56.06 g/mol
Salts & Minerals Textile, Leather & PaperMining & MetalsOil, Gas & EnergyPulp & PaperWater Treatment CatalysisPreservation & BiocidepH Regulation & BufferingFlame Retardancy

Description

Sodium hydrosulfide (CAS 16721-80-5), also known as sodium bisulfide or sodium mercaptan, is an inorganic sulfur compound with the formula HNaS. It carries no assigned E-code and is commercially supplied as a solid or in aqueous solution. It is registered under EC number 240-778-0.

In leather processing, sodium hydrosulfide depilates hides by breaking disulfide bonds in keratin, enabling efficient hair removal without mechanical damage. In mining, it selectively activates sulfide mineral surfaces during froth flotation, improving metal recovery rates. Water treatment facilities use it to reduce hexavalent chromium and neutralize oxidising agents in industrial effluent.

Sodium hydrosulfide is available in technical and industrial grades, supplied as crystalline solid or aqueous solution, typically in concentrations of 70-72% flake or 25-45% liquid. It falls under REACH regulation and requires a Safety Data Sheet compliant with EU GHS standards. Packaging formats include drums, IBCs, and bulk tanker delivery for liquid grades.

Physical Properties

Melting Point 350 °C
Density 1.79 g/cm³
Flash Point 90°C
Appearance white crystals or powder with a very unpleasant smell
Color Off-white
Form Solid
Water Solubility 620 g/L (20 ºC)

Safety & Handling (Learn More)

Danger GHS02 GHS05 GHS06 GHS09 GHS07 GHS08
H
H226H251H290H301H312H314H318H335H371H400
P
P210P233P234P235P240P241P242P243P260P261P264P270P271P273P280P316P317P319P321P330P363P390P391P405P406P407P410P413P420P501P264+P265P301+P316P302+P352P304+P340P308+P316P362+P364P370+P378P403+P233P403+P235P301+P330+P331P302+P361+P354P303+P361+P353P305+P354+P338

Other Names

sodium sulfanidesodium sulfidesodium mercaptanSodium Bisulfidesodium sulfhydrateNaHSSodium mercaptide

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