SoleChem

Tbdmscl

CAS 18162-48-6
EC 242-042-4
Formula C6H15ClSi
MW 150.72 g/mol
Organometallic Compounds Biotechnology & Life SciencesPharmaceuticals & HealthcarePlastics & PolymersElectronics Cross-linking & CuringSurface Modification & WettingSolvent & Carrier

Description

TBDMS chloride (CAS 18162-48-6, EC 242-042-4) is an organosilicon reagent used to introduce tert-butyldimethylsilyl protecting groups onto hydroxyl and other nucleophilic functional groups. Also known as TBDMSCL, TBSCL, TBDMCS, and TBDMSCl, it carries no assigned E-code and is classified under HS code 29310095.

In pharmaceutical synthesis, TBDMS chloride selectively protects alcohol and amine groups during multi-step reactions, allowing subsequent transformations to proceed without unwanted side reactions. In electronics and polymer applications, it functions as a surface modifier and crosslinker by reacting with silanol groups on substrates, improving adhesion and controlling wetting behaviour at interfaces.

TBDMS chloride is supplied as a technical-grade solid or liquid and is subject to REACH registration requirements within the European Economic Area. Procurement teams should confirm purity specifications and SDS documentation prior to ordering, as grade requirements vary between pharmaceutical and industrial polymer applications.

Physical Properties

Melting Point 112-114 °C
Boiling Point 126.00 °C
Density 0.872 g/cm³
Flash Point 73 °F
Appearance White solid
Color Clear colorless
Form Liquid
Water Solubility Soluble in chloroform and ethyl acetate. Insoluble in water.
Vapor Pressure 60-710Pa at 25℃
Refractive Index n 20/D 1.46
Log P 2.5 at 20℃

Safety & Handling (Learn More)

Danger GHS02 GHS05 GHS07 GHS09
H
H228H314H318H335H411
P
P210P240P241P260P261P264P271P273P280P316P317P319P321P363P391P405P501P264+P265P304+P340P370+P378P403+P233P301+P330+P331P302+P361+P354P305+P354+P338

Trade & Regulatory

HS Code 29310095
UN Number 2925
ADR Class 4.1
Packing Group II
Storage Class 4.1B - Flammable solid hazardous materials
WGK (Germany) 2

Other Names

Tert-Butyldimethylsilyl Chloridetert-butyl-chloro-dimethylsilaneTBDMS chloridet-butyldimethylchlorosilanetert-butyldimethylchlorosilaneBDCSTBSCLTBDMCl

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