SoleChem

Tert-Butyl peroxybenzoate

CAS 614-45-9
EC 210-382-2
Formula C11H14O3
MW 194.23 g/mol
Oxidizers & Peroxides Plastics & PolymersCoatings, Adhesives, Sealants & ElastomersRubber & TireFood & NutritionPersonal Care & Cosmetics Cross-linking & CuringCatalysisPreservation & BiocideAntioxidant & Stabilizer

Description

Tert-Butyl peroxybenzoate (CAS 614-45-9) is an organic peroxide supplied under trade names including Trigonox C, Perbutyl Z, Esperox 10, Chaloxyd TBPB, and VAROX TBPB. It belongs to the peroxyester class and decomposes thermally to generate free radicals, making it reactive across a range of industrial processes.

In polymer manufacturing, it initiates crosslinking of polyester resins and silicone rubbers by generating radicals that form covalent bonds between polymer chains, increasing mechanical strength and heat resistance. It also functions as a high-temperature cure initiator for unsaturated polyesters in coatings and composite applications, where its half-life temperature profile suits elevated-temperature processing cycles.

This product is available in liquid form and supplied under REACH compliance for European markets. It carries an HS code of 29163900 and is handled under organic peroxide transport regulations. Procurement teams should confirm concentration grade and packaging format, as these determine classification and storage requirements.

Physical Properties

Melting Point 8 °C
Boiling Point 75-76 °C @ Press: 0.2 Torr
Density 1.021 g/cm³ @ Temp: 25 °C
Flash Point 200 °F
Appearance colourless or slightly yellow liquid
Color Clear yellow
Odor mild aromatic odor
Form Liquid
Water Solubility Immiscible
Vapor Pressure 3.36 mm Hg ( 50 °C)
Refractive Index n 20/D 1.499(lit.)
Log P 3 at 25℃

Safety & Handling (Learn More)

Danger GHS02 GHS07 GHS09 GHS08
H
H227H242H315H317H320H332H371H400H410H412
P
P210P234P235P240P260P261P264P270P271P272P273P280P317P321P391P403P405P410P411P420P501P264+P265P302+P352P304+P340P308+P316P332+P317P333+P317P337+P317P362+P364P370+P378P305+P351+P338

Trade & Regulatory

HS Code 29163900
UN Number 3103
ADR Class 5.2
Storage Class 4.1A - Other explosive hazardous materials
WGK (Germany) 2

Other Names

tert-butyl benzenecarboperoxoateTBPBPerbutyl ZVAROX TBPBEsperox 10Chaloxyd TBPBTRIGONOX(R) C

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