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Tetrafluoroboric acid

CAS 16872-11-0
EC 240-898-3
Formula BF4.H
MW 63.82 g/mol
Inorganic Acids Mining & MetalsLubricants & MetalworkingPlastics & PolymersElectronics CatalysispH Regulation & BufferingCorrosion Inhibition

Description

Tetrafluoroboric acid (CAS 16872-11-0, EC 240-898-3), also known as fluoboric acid or borofluoric acid, is an inorganic acid supplied exclusively as an aqueous solution. It carries no E-code designation and is classified under HS code 28111990 within the inorganic acids category.

In electronics manufacturing, tetrafluoroboric acid serves as an electrolyte in tin and lead electroplating baths, where fluoroborate ions stabilise metal deposition at controlled rates. In mining and metals processing, it acts as a pH regulator and catalyst in flux formulations, facilitating oxide removal from metal surfaces prior to soldering or coating operations.

Tetrafluoroboric acid is available in technical and high-purity grades as aqueous solutions of varying concentration, typically ranging from 40% to 50% w/w. The substance is registered under REACH and subject to standard industrial handling classifications. Packaging is available in drums and intermediate bulk containers to suit procurement volumes.

Physical Properties

Melting Point -90°C
Boiling Point 130°C (dec.)
Density ~1.84 g/cm³ (approx)
Flash Point −40 °F
Appearance Fluoboric acid is a colorless liquid which does not exist as a free, pure substance. Used as an aqueous solution.
Color Light Yellow
Odor Odorless
Form Liquid
Water Solubility MISCIBLE
Vapor Pressure 5 mmHg ( 20 °C)
Refractive Index nD20 of a 20% aq soln 1.3284

Safety & Handling (Learn More)

Danger GHS05 GHS06 GHS07 GHS08
H
H290H301H311H314H318H335H336H371H372
P
P234P260P261P262P264P270P271P280P316P317P319P321P330P363P390P405P406P501P264+P265P301+P316P302+P352P304+P340P308+P316P361+P364P403+P233P301+P330+P331P302+P361+P354P305+P354+P338

Trade & Regulatory

HS Code 28111990
UN Number 1775
ADR Class 8
Packing Group II
Storage Class 8B - Non-combustible corrosive hazardous materials
WGK (Germany) 1

Other Names

hydron tetrafluoroborateHBF4fluoboric acidfluoroboric acidborofluoridBorofluoric acid

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