SoleChem

Triethylborane

CAS 97-94-9
EC 202-620-9
Formula C6H15B
MW 97.99 g/mol
Organometallic Compounds Plastics & PolymersBiotechnology & Life SciencesPharmaceuticals & HealthcareAerospace & Defense Polymerization InitiationCatalysis

Description

Triethylborane (CAS 97-94-9), also known as TEB, Borethyl, or boron ethyl, is an organoboron compound with the formula (C2H5)3B. It carries no assigned E-code and is classified under HS code 29319090. It is commercially available as a clear colourless to light amber liquid solution.

In polyolefin production, TEB acts as a co-catalyst alongside Ziegler-Natta systems, activating transition metal centres to initiate controlled chain growth. It is also used in pharmaceutical synthesis as a radical initiator, generating ethyl radicals at low temperatures to drive selective carbon-carbon bond-forming reactions in complex molecule construction.

TEB is supplied in stabilised solution grades formulated for handling safety, given its pyrophoric nature. It is subject to REACH registration requirements within the EU and must be handled under inert atmosphere conditions. Packaging is typically provided in specialised sealed containers appropriate for air-sensitive materials.

Physical Properties

Melting Point -92.9 °C
Boiling Point 95-96 °C
Density 0.697 g/cm³ @ Temp: 20 °C
Flash Point 1 °F
Appearance CLEAR COLOURLESS TO LIGHT AMBER SOLUTION
Color Colorless to light amber
Form Liquid
Water Solubility Decomposes
Vapor Pressure 67hPa at 25℃
Refractive Index n 20/D 1.380

Safety & Handling (Learn More)

Danger GHS02 GHS05 GHS06 GHS08
H
H225H250H301H314H318H330H331H360
P
P203P210P222P231P233P240P241P242P243P260P261P264P270P271P280P284P316P317P318P320P321P330P363P405P501P264+P265P301+P316P304+P340P370+P378P403+P233P403+P235P301+P330+P331P302+P335+P334P302+P361+P354P303+P361+P353P305+P354+P338

Trade & Regulatory

HS Code 29319090
UN Number 3399
ADR Class 4.3
Packing Group II
WGK (Germany) 2

Other Names

TEBtriethylboron(C2H5)3BBorethylBoron ethyltriethyl-boranBORON TRIETHYL

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