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Triphenylphosphine

CAS 603-35-0
EC 210-036-0
Formula C18H15P
MW 262.29 g/mol
Catalysts & Catalyst Precursors Pharmaceuticals & HealthcarePrinting & PackagingPlastics & PolymersPersonal Care & Cosmetics CatalysisUV Protection & StabilizationFlavoring & Acidulant

Description

Triphenylphosphine (CAS 603-35-0) is an organophosphorus compound commercially available under trade names including P 100, PP-360, and JC 263, with the abbreviation TRP also in common use. It carries no assigned E-code. It is classified under HS code 29310095 and belongs to the catalysts and catalyst precursors category.

In pharmaceutical synthesis, triphenylphosphine drives Wittig and Mitsunobu reactions by acting as a nucleophilic phosphorus donor, enabling precise carbon-carbon and carbon-heteroatom bond formation. In polymer and plastics processing, it functions as a stabilizer and catalyst precursor, coordinating with transition metals to form active catalytic complexes that control polymerization selectivity.

Triphenylphosphine is supplied as crystalline powder or flakes and is subject to REACH registration requirements for European procurement. Buyers should confirm supplier compliance documentation and grade specification, as purity requirements differ between pharmaceutical and industrial polymer applications. Standard packaging formats vary by supplier volume tier.

Physical Properties

Melting Point 80.5 °C
Boiling Point >360 °C
Density 1.075 g/cm³ @ Temp: 80 °C
Flash Point 181 °C
Appearance White, crystalline solid. Insoluble inwater; slightly soluble in alcohol; soluble in benzene, acetone, carbon tetrachloride. Combustible.
Color White
Odor odorless
Form Crystals, Crystalline Powder or Flakes
Water Solubility Insoluble
Vapor Pressure 5 mm Hg ( 20 °C)
Refractive Index 1.6358

Safety & Handling (Learn More)

Warning GHS05 GHS07 GHS08
H
H302H315H317H318H319H335H350H372H373H412H413
P
P203P260P261P264P270P271P272P273P280P317P318P319P321P330P405P501P264+P265P301+P317P302+P352P304+P340P332+P317P333+P317P337+P317P362+P364P403+P233P305+P351+P338P305+P354+P338

Trade & Regulatory

HS Code 29310095
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 2

Other Names

TriphenylphosphaneTPPTRPP 100PP-360JC 263PP 360'LGC' (4006)

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