1,4-Butanediol dimethacrylate

CAS Number
2082-81-7
EC Number
218-218-1
Abbreviation
BDDMA

What is 1,4-Butanediol dimethacrylate?

1,4-Butanediol dimethacrylate (CAS 2082-81-7), commonly abbreviated as BDDMA, is a bifunctional methacrylate monomer used as a crosslinking agent in polymer and coating systems.

Where is 1,4-Butanediol dimethacrylate used?

  • UV- and peroxide-cured coatings: increases crosslink density, giving harder, more chemically resistant films on wood, metal, and plastic
  • Adhesives and sealants: tunes cohesive strength and flexibility in structural systems
  • Plastics and polymer manufacturing: crosslinker in suspension polymerization for beads and resins with controlled swelling behaviour, a critical parameter for ion-exchange media
  • Personal care: builds film-forming polymer networks in nail gels and colour cosmetics
  • By linking polymer chains at two reactive sites it controls network density, hardness, and solvent resistance in cured materials.

Good to know: Cure speed and film integrity are evaluated during qualification for these applications.

Commercial specifications

  • Standard commercial grades at purities of 97% and above
  • Inhibitor type and concentration specified on the product data sheet

Other Names (Synonyms)

4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate|Butanediol dimethacrylate|BDDMA

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What are the physical properties of 1,4-Butanediol dimethacrylate?

Melting Point 226.28 °C
Boiling Point 110 °C @ Press: 3 Torr
Density 1.011 g/cm³ @ Temp: 25 °C
Flash Point 38 °F
Color Clear colorless to slightly yellow
Form Liquid
Water Solubility 243mg/L at 20℃
Vapor Pressure 430 mm Hg ( 25 °C)
Refractive Index n 20/D 1.456(lit.)
Log P 3.1 at 20℃

How is 1,4-Butanediol dimethacrylate classified and handled safely? Learn More

Warning
GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H361 Suspected of damaging fertility or the unborn child
H401 Toxic to aquatic life

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.

Which trade and regulatory codes apply to 1,4-Butanediol dimethacrylate?

HS Code 29161400
UN Number 2924
ADR Class 3
Packing Group II
Storage Class 10 - Combustible liquids
WGK (Germany) 2
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