Sodium sulfide

CAS Number
1313-82-2
EC Number
215-211-5

What is Sodium sulfide?

Sodium sulfide (CAS 1313-82-2), also known as disodium sulfide, is an inorganic sulfur compound supplied primarily in hydrated flake form.

Where is Sodium sulfide used?

  • Leather tanning: primary unhairing agent that breaks down keratin bonds in hides during the beamhouse stage
  • Textile dyeing: reducing agent that solubilizes sulfur dyes for coloration on cotton and cellulosic fibers
  • Mining and hydrometallurgy: precipitates heavy metal ions from process streams and leachates
  • Paper pulp and water treatment: sulfide precipitation and pH adjustment
  • It functions as a reducing and precipitating agent in heavy industrial processes.
  • Water treatment: acts as an oxygen scavenger to prevent corrosion in pipelines.
  • Photographic industry: used as a color developer.
  • Ceramics: used as a depressant for quartz.
  • Low-iron sodium sulfide is preferred in applications where high purity is crucial and iron could negatively affect the process or final product quality.

Good to know: Technical grade is the standard market form; anhydrous and higher-purity grades exist for specialty applications but are less common in bulk industrial trade.

Formulation notes

  • Keep away from acids and oxidizing agents.
  • Reacts violently with oxidants.

Typical specification

  • Supplied at a minimum assay of 90% (iodimetry), with the balance being water.
  • The strongest grade has an iron content below 10 ppm.
  • Sodium sulfide Fe 30PP is a specific grade containing a higher iron concentration, generally around 30 ppm.

Regulatory status

  • Classified under UN transport Class 4.2 with Packing Group II.
  • Has the EU CLP index number 016-009-00-8.
  • Classified as corrosive to metals Category 1 (H290).

Storage, packaging and handling

  • Commonly available in lined Jumbo Big Bags.
  • Keep in tightly closed containers.

Frequently asked questions about Sodium sulfide

In which mineral processing operations is sodium sulfide used as a sulfidizing reagent?
It is used as a sulfidizing reagent in the flotation preparation of oxidized, metallic copper, zinc, and lead minerals.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

Disodium sulphide|Disodium sulfide (Na2S)|RefChem:887903|Sodium sulfide (Na2S)|Sodium monosulfide

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What are the physical properties of Sodium sulfide?

Melting Point 83 °C
Density 1.856 g/cm³ @ Temp: 14 °C
Appearance crystals of varied colour, with a repulsive odour
Color Yellow
Odor Rotten egg odor
Form flakes
Water Solubility 186 g/L (20 ºC)

How is Sodium sulfide classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS09· Environmental Hazard GHS02· Flammable GHS08· Health Hazard

Hazard Statements

H251 Self-heating; may catch fire
H290 May be corrosive to metals
H301 Toxic if swallowed
H302 Harmful if swallowed

Precautionary Statements

P234 Keep only in original packaging.
P235 Keep cool.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

Which trade and regulatory codes apply to Sodium sulfide?

HS Code 28301010
UN Number 1849
ADR Class 8
Packing Group II
Storage Class 4.2 - Pyrophoric and self-heating hazardous materials
WGK (Germany) 2
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