1-Dodecanethiol

CAS Number
112-55-0
EC Number
203-984-1
Chemical Formula
C12H26S
Molecular Weight
202.40 g/mol
FEMA Number
FEMA 4581

Description

1-Dodecanethiol (CAS 112-55-0), commercially known as dodecyl mercaptan, is a long-chain aliphatic thiol used as a chain transfer agent, flavoring component, and chemical intermediate across multiple industries. Its primary industrial role is controlling polymer molecular weight during free-radical polymerization and providing sulfurous flavor notes at trace concentrations. In polymer manufacturing, it regulates chain length during production.

This process is essential for synthetic rubbers, ABS resins, and styrene-butadiene latex, directly influencing the mechanical properties of the finished material. In food flavoring, it contributes characteristic roasted, meaty, and savory notes. These flavor compositions are effective at very low use levels. Personal care formulators incorporate it as a building block for sulfur-containing surfactants and conditioning agents used in various hair care products.

Coatings and adhesive manufacturers also use it as a surface modifier and stabilizer to improve adhesion and extend shelf life of reactive formulations. It is supplied as a clear to pale yellow liquid in drum and IBC quantities. Technical grade is the standard commercial offering, suitable for polymer and industrial applications. Food-grade material meeting FCC specifications is available for flavor and fragrance end uses.

Other Names (Synonyms)

Dodecyl mercaptan|Dodecane-1-thiol

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -7 °C
Boiling Point 142-145 °C @ Press: 15 Torr
Density 0.8450 g/cm³ @ Temp: 20 °C
Flash Point >230 °F
Appearance clear liquid
Color Clear
Odor Stench
Form Liquid
Water Solubility IMMISCIBLE
Vapor Pressure 0.002 hPa (20 °C)
Refractive Index n 20/D 1.459(lit.)
Log P 6.18

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard

Hazard Statements

H302 Harmful if swallowed
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation

Precautionary Statements

P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Trade & Regulatory

HS Code 29309070
UN Number 1208
ADR Class 3
Packing Group II
Storage Class 8A - Combustible corrosive hazardous materials
WGK (Germany) 3
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