1-octanethiol

CAS Number
111-88-6
EC Number
203-918-1
Chemical Formula
C8H18S
Molecular Weight
146.30 g/mol

Description

1-Octanethiol (CAS 111-88-6), also known commercially as n-octyl mercaptan, is a sulfur-containing organic compound used as a chain transfer agent in polymer synthesis. It serves as a chemical intermediate across specialty chemical manufacturing. Its reactive thiol group makes it a functional building block in pharmaceutical and industrial processes. In polymer production, it controls molecular weight during free-radical polymerization of acrylates, styrene, and vinyl acetate.

This directly influences the mechanical properties of the final resin. The pharmaceutical industry uses it as a synthetic intermediate in the preparation of active ingredients and sulfur-containing compounds for various medical applications. In lubricant formulations, it contributes to extreme-pressure additive packages for metalworking fluids. Here, sulfur-based chemistry provides boundary lubrication under high-load conditions to protect machinery and tools.

It also functions as a coupling agent and surface modifier for metal nanoparticles and quantum dots in specialty materials applications. This versatility makes it essential for advanced material science and electronics. The product is supplied as a clear liquid in standard packaging ranging from drums to ISO containers, depending on volume requirements. Technical grade is the most common commercial specification for industrial use.

High-purity grades are available for pharmaceutical and specialty materials applications. Suppliers typically offer material with purity levels of 98% or higher to meet strict manufacturing requirements. Certificate of analysis documentation is standard for regulated-industry procurement. This ensures that the material meets the necessary safety and performance benchmarks for global chemical distribution and logistics.

Other Names (Synonyms)

n-octyl mercaptan|1-octylthiol|1-mercaptooctane|Octane-1-thiol|Octyl mercaptan|n-Octanethiol

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -49.2 °C
Boiling Point 86 °C @ Press: 15 Torr
Density 0.8433 g/cm³ @ Temp: 20 °C
Flash Point 55 °F
Appearance colourless liquid
Color Clear colorless
Odor Sulfurous
Form Liquid
Water Solubility Not miscible in water.
Vapor Pressure 0.3 hPa (20 °C)
Refractive Index n 20/D 1.452(lit.)
Log P 4.21 at 20℃

Documentation

Safety & Handling Learn More

Warning
GHS07· Irritant GHS09· Environmental Hazard GHS08· Health Hazard

Hazard Statements

H227 Combustible liquid
H302 Harmful if swallowed
H312 Harmful in contact with skin
H315 Causes skin irritation

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Trade & Regulatory

HS Code 29309070
UN Number 1170
ADR Class 3
Packing Group II
Storage Class 10 - Combustible liquids
WGK (Germany) 3
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