1-octanethiol
Description
1-Octanethiol (CAS 111-88-6), also known commercially as n-octyl mercaptan, is a sulfur-containing organic compound used as a chain transfer agent in polymer synthesis. It serves as a chemical intermediate across specialty chemical manufacturing.
Its reactive thiol group makes it a functional building block in pharmaceutical and industrial processes. In polymer production, it controls molecular weight during free-radical polymerization of acrylates, styrene, and vinyl acetate.
This directly influences the mechanical properties of the final resin. The pharmaceutical industry uses it as a synthetic intermediate in the preparation of active ingredients and sulfur-containing compounds for various medical applications.
In lubricant formulations, it contributes to extreme-pressure additive packages for metalworking fluids. Here, sulfur-based chemistry provides boundary lubrication under high-load conditions to protect machinery and tools.
It also functions as a coupling agent and surface modifier for metal nanoparticles and quantum dots in specialty materials applications. This versatility makes it essential for advanced material science and electronics.
The product is supplied as a clear liquid in standard packaging ranging from drums to ISO containers, depending on volume requirements. Technical grade is the most common commercial specification for industrial use.
High-purity grades are available for pharmaceutical and specialty materials applications. Suppliers typically offer material with purity levels of 98% or higher to meet strict manufacturing requirements.
Certificate of analysis documentation is standard for regulated-industry procurement. This ensures that the material meets the necessary safety and performance benchmarks for global chemical distribution and logistics.
Physical Properties
| Melting Point | -49.2 °C |
| Boiling Point | 86 °C @ Press: 15 Torr |
| Density | 0.8433 g/cm³ @ Temp: 20 °C |
| Flash Point | 55 °F |
| Appearance | colourless liquid |
| Color | Clear colorless |
| Odor | at 0.10?%?in?dipropylene glycol. sulfurous |
| Form | Liquid |
| Water Solubility | Not miscible in water. |
| Vapor Pressure | 0.3 hPa (20 °C) |
| Refractive Index | n 20/D 1.452(lit.) |
| Log P | 4.21 at 20℃ |
Safety & Handling (Learn More)
Trade & Regulatory
| HS Code | 29309070 |
| UN Number | 1170 |
| ADR Class | 3 |
| Packing Group | II |
| Storage Class | 10 - Combustible liquids |
| WGK (Germany) | 3 |
Documentation
Other Names
n-octyl mercaptan|1-octylthiol|1-mercaptooctane|Octane-1-thiol|Octyl mercaptan|n-Octanethiol
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