Butanethiol

CAS Number
109-79-5
EC Number
203-705-3
Chemical Formula
C4H10S
Molecular Weight
90.19 g/mol
FEMA Number
FEMA 3478

Description

Butanethiol (CAS 109-79-5), also known as n-butyl mercaptan, is a sulfur-containing organic compound used commercially as an odorant and flavoring agent. Its intensely low odor threshold makes it effective for gas leak detection and trace-level sensory applications. FEMA 3478 designates it as an approved flavoring substance for food use. In the oil and gas industry, butanethiol is blended into natural gas and LPG as a stenching agent, providing the characteristic warning odor.

This warning odor enables leak detection at extremely low concentrations. Food and beverage formulators use it at trace levels to contribute sulfurous, onion-like, or savory top notes in processed flavors for various applications. It functions as a building block in flavor systems targeting meat, roasted, and allium profiles. Fragrance and flavor houses also incorporate it into reference standards and specialty aroma compositions requiring controlled sulfur character.

Butanethiol is supplied as a liquid, typically in small containers suited to its high odor intensity and handling requirements. It is available in technical grade for industrial odorant applications and in food-grade specifications. The material is compliant with FEMA and relevant flavor safety standards. Packaging ranges from laboratory-scale quantities to drum volumes depending on end-use volume requirements and specific industrial or food-grade needs.

Other Names (Synonyms)

n-Butyl mercaptan|n-Butanethiol|1-Mercaptobutane|1-Butanethiol|butane-1-thiol|BUTYL MERCAPTAN|Thiobutyl alcohol|n-Butyl thioalcohol

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -115.7 °C
Boiling Point 98.4 °C @ Press: 760 Torr
Density 0.8337 g/cm³ @ Temp: 20 °C
Flash Point 55 °F
Appearance colourless liquid
Color Colorless
Odor Strong skunk-like.
Form Liquid
Water Solubility 0.60 g/100 mL. Slightly soluble
Vapor Pressure 83 mm Hg ( 37.7 °C)
Refractive Index n 20/D 1.443(lit.)
Log P 2.28

Documentation

Safety & Handling Learn More

Danger
GHS02· Flammable GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H225 Highly Flammable liquid and vapor
H302 Harmful if swallowed
H316 Causes mild skin irritation
H317 May cause an allergic skin reaction

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.

Trade & Regulatory

HS Code 2930 90 98
UN Number 2347
ADR Class 3
Packing Group II
Storage Class 3 - Flammable liquids
WGK (Germany) 3
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