SoleChem

Butanethiol

CAS
109-79-5
EC
203-705-3
Mol. Weight
90.19 g/mol

Description

Butanethiol (CAS 109-79-5), also known as n-butyl mercaptan, is a sulfur-containing organic compound used commercially as an odorant and flavoring agent. Its intensely low odor threshold makes it effective for gas leak detection and trace-level sensory applications.

FEMA 3478 designates it as an approved flavoring substance for food use. In the oil and gas industry, butanethiol is blended into natural gas and LPG as a stenching agent, providing the characteristic warning odor.

This warning odor enables leak detection at extremely low concentrations. Food and beverage formulators use it at trace levels to contribute sulfurous, onion-like, or savory top notes in processed flavors for various applications.

It functions as a building block in flavor systems targeting meat, roasted, and allium profiles. Fragrance and flavor houses also incorporate it into reference standards and specialty aroma compositions requiring controlled sulfur character.

Butanethiol is supplied as a liquid, typically in small containers suited to its high odor intensity and handling requirements. It is available in technical grade for industrial odorant applications and in food-grade specifications.

The material is compliant with FEMA and relevant flavor safety standards. Packaging ranges from laboratory-scale quantities to drum volumes depending on end-use volume requirements and specific industrial or food-grade needs.

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Physical Properties

Melting Point -115.7 °C
Boiling Point 98.4 °C @ Press: 760 Torr
Density 0.8337 g/cm³ @ Temp: 20 °C
Flash Point 55 °F
Appearance colourless liquid
Color Colorless
Odor Strong skunk-like.
Form Liquid
Water Solubility 0.60 g/100 mL. Slightly soluble
Vapor Pressure 83 mm Hg ( 37.7 °C)
Refractive Index n 20/D 1.443(lit.)
Log P 2.28

Safety & Handling (Learn More)

Danger GHS02 GHS07 GHS08
Hazard Statements
H225 Highly Flammable liquid and vapor
H302 Harmful if swallowed
H316 Causes mild skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H320 Causes eye irritation
H332 Harmful if inhaled
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H361 Suspected of damaging fertility or the unborn child
H370 Causes damage to organs
H371 May cause damage to organs
Precautionary Statements
P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P317 Get emergency medical help.
P318 IF exposed or concerned, get medical advice.
P319 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P317 Get emergency medical help.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P316 Get emergency medical help immediately.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 2930 90 98
UN Number 2347
ADR Class 3
Packing Group II
Storage Class 3 - Flammable liquids
WGK (Germany) 3

Documentation

Other Names

n-Butyl mercaptan|n-Butanethiol|1-Mercaptobutane|1-Butanethiol|butane-1-thiol|BUTYL MERCAPTAN|Thiobutyl alcohol|n-Butyl thioalcohol

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