Tetrahydrothiophene

CAS Number
110-01-0
EC Number
203-728-9
Chemical Formula
C4H8S
Molecular Weight
88.17 g/mol
Abbreviation
THT

Description

Tetrahydrothiophene (CAS 110-01-0), also known as THT and thiophane, is a saturated sulfur-containing heterocyclic compound used commercially as an odorant and corrosion inhibitor across energy and industrial sectors. Its distinctive, persistent odor makes it the standard gas-odorization agent in natural gas and LPG distribution networks across Europe and many other markets. THT is injected into natural gas and liquefied petroleum gas pipelines.

This injection occurs at low concentrations to provide the characteristic warning odor required by safety regulations, enabling leak detection by end users. In industrial cleaning and maintenance formulations, it functions as a sulfur-based corrosion inhibitor. It protects metal surfaces exposed to aggressive process environments. Water treatment operations use THT-based chemistry where controlled sulfur dosing is required to manage scaling or microbial activity in distribution systems.

As a flavoring reference compound, it is also evaluated in fragrance and flavor research for its role in characterizing sulfurous aroma profiles. Tetrahydrothiophene is supplied as a clear liquid in drums and IBCs. Bulk tanker quantities are also available, suited to pipeline odorization programs. Technical-grade material is the standard commercial form, with purity specifications typically at 98% or higher.

Specialty grades meeting tighter purity thresholds are available for analytical and flavor research applications. These high-purity options ensure consistent performance in sensitive laboratory and industrial environments.

Other Names (Synonyms)

thiophane|thiolan|tetramethylene sulfide|THT|Thiolane|Thiophene, tetrahydro-|Thilane|4-Butylene Sulfide

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point -96.16 °C
Boiling Point 121.12 °C @ Press: 760 Torr
Density 0.9987 g/cm³ @ Temp: 20 °C
Flash Point 55 °F
Appearance colourless liquid
Color Colorless to Almost colorless
Odor Smells of rotting eggs
Form liquid
Water Solubility immiscible
Vapor Pressure 18 mm Hg ( 25 °C)
Refractive Index n 20/D 1.504(lit.)
pH 7 (H2O, 20℃)
Log P 1.8 at 20℃

Documentation

Safety & Handling Learn More

Danger
GHS02· Flammable GHS07· Irritant

Hazard Statements

H225 H225
H302 H302
H312 H312
H315 H315

Precautionary Statements

P210 P210
P233 P233
P240 P240
P241 P241

Trade & Regulatory

HS Code 29349990
UN Number 2412
ADR Class 3
Packing Group II
Storage Class 3 - Flammable liquids
WGK (Germany) 2
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