Tetrahydrothiophene

CAS Number
110-01-0
EC Number
203-728-9
Abbreviation
THT

What is Tetrahydrothiophene?

Tetrahydrothiophene (CAS 110-01-0), also known as THT and thiophane, is a saturated sulfur-containing heterocyclic compound used commercially as an odorant and corrosion inhibitor.

Where is Tetrahydrothiophene used?

  • Natural gas and LPG distribution: standard gas-odorization agent, injected into pipelines at low concentrations to provide the warning odor required by safety regulations, enabling leak detection by end users
  • Industrial cleaning and maintenance: sulfur-based corrosion inhibitor protecting metal surfaces exposed to aggressive process environments
  • Water treatment: THT-based chemistry where controlled sulfur dosing is required to manage scaling or microbial activity in distribution systems
  • Fragrance and flavor research: it is evaluated as a flavoring reference compound for characterizing sulfurous aroma profiles.

Commercial specifications

  • Technical grade: purity typically 98% or higher
  • Specialty grades with tighter purity thresholds for analytical and flavor research
  • Clear liquid in drums and IBCs; bulk tanker quantities for pipeline odorization programs

Other Names (Synonyms)

thiophane|thiolan|tetramethylene sulfide|THT|Thiolane|Thiophene, tetrahydro-|Thilane|4-Butylene Sulfide

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What are the physical properties of Tetrahydrothiophene?

Melting Point -96.16 °C
Boiling Point 121.12 °C @ Press: 760 Torr
Density 0.9987 g/cm³ @ Temp: 20 °C
Flash Point 55 °F
Appearance colourless liquid
Color Colorless to Almost colorless
Odor Smells of rotting eggs
Form liquid
Water Solubility immiscible
Vapor Pressure 18 mm Hg ( 25 °C)
Refractive Index n 20/D 1.504(lit.)
pH 7 (H2O, 20℃)
Log P 1.8 at 20℃

How is Tetrahydrothiophene classified and handled safely? Learn More

Danger
GHS02· Flammable GHS07· Irritant

Hazard Statements

H225 H225
H302 H302
H312 H312
H315 H315

Precautionary Statements

P210 P210
P233 P233
P240 P240
P241 P241

Which trade and regulatory codes apply to Tetrahydrothiophene?

HS Code 29349990
UN Number 2412
ADR Class 3
Packing Group II
Storage Class 3 - Flammable liquids
WGK (Germany) 2
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