SoleChem

Ethyl hexanoate

CAS
123-66-0
EC
204-640-3
Mol. Weight
144.21 g/mol

Description

Ethyl hexanoate (CAS 123-66-0), also known by its FEMA 2439 designation and commercially as ethyl caproate, is a fruity ester used as a flavoring agent and fragrance ingredient across food, cosmetic, and industrial applications.

Its characteristic apple-pineapple odor profile makes it a target compound for flavor houses and fragrance formulators sourcing aroma chemicals at scale. In food and beverage manufacturing, it functions as a flavoring agent.

It is used in fruit-type confectionery, alcoholic beverages, and dairy products where tropical and apple notes are required. Fragrance formulators incorporate it into personal care products including lotions, shampoos, and body washes.

These applications deliver light, fresh top notes to the consumer. As a synthetic ester, it also sees use as a lubricant additive and plasticizer component in specialty industrial formulations where low-viscosity ester chemistry is specified.

Flavor blenders reference its regulatory status when qualifying it for use in regulated food applications in the US market. The compound is supplied as a clear liquid in drum and IBC quantities suited to industrial procurement.

It is available in food-grade and fragrance-grade specifications, with FCC grade material commonly requested for flavor applications. Purity levels of 98% and above are standard for flavor and fragrance end uses.

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Physical Properties

Melting Point -67 °C
Boiling Point 165.6 °C
Density 0.83146 g/cm³ @ Temp: 70.00 °C
Flash Point 121 °F
Appearance CLEAR COLOURLESS LIQUID
Color Clear colorless
Odor at 1.00 % in dipropylene glycol. sweet fruity pineapple waxy green banana
Form Liquid
Water Solubility INSOLUBLE
Vapor Pressure 4hPa at 25℃
Refractive Index n 20/D 1.407
Log P 2.96 at 22.4℃

Safety & Handling (Learn More)

Warning GHS02 GHS09
Hazard Statements
H226 Flammable liquid and vapor
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local regulations.
P370+P378 Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

Trade & Regulatory

HS Code 29159000
UN Number 3272
ADR Class 3
Packing Group III
Storage Class 3 - Flammable liquids
WGK (Germany) 1

Documentation

Other Names

n-Caproic acid ethyl ester|Hexanoic acid, ethyl ester|Ethyl n-hexanoate|Ethyl n-hexanoat|Ethyl hexoate|Ethyl hexanoate (caproate)|Ethyl ester of hexanoic acid

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