Calcium nitrite

CAS Number
13780-06-8
EC Number
237-424-2
Chemical Formula
Ca.2HNO2
Molecular Weight
132.09 g/mol

Description

Calcium nitrite (CAS 13780-06-8) is an inorganic calcium salt used industrially as a corrosion inhibitor and accelerating admixture in construction and infrastructure applications. It is occasionally referenced under the Caswell No. 147 designation in regulatory contexts. Its primary commercial value lies in protecting embedded steel reinforcement from chloride-induced corrosion while simultaneously accelerating early concrete strength development. In reinforced concrete structures, it is dosed as an admixture to extend service life.

Bridges, parking decks, marine infrastructure, and below-grade foundations utilize this chemical in chloride-rich environments. Precast concrete producers use it to shorten demolding cycles by accelerating cement hydration at lower temperatures. In oil and gas well cementing, it functions as a set accelerator under cold downhole conditions. The mining sector uses the compound in grouting operations and in corrosion protection treatments for steel ground support elements.

Calcium nitrite is supplied primarily as an aqueous solution, with 30% and 35% concentrations being the most commercially standard for concrete admixture use. Solid forms, including powder and granules, are available for specific applications. These solid formats are preferred where liquid handling or freight costs are a constraint. Technical grade is the predominant specification across construction and mining end uses, ensuring reliable performance in heavy industrial settings.

Other Names (Synonyms)

calcium dinitrite|Nitrous acid, calcium salt|Caswell No. 147|Nitrous acid calcium salt (2:1)|EPA Pesticide Chemical Code 076202|F538343O0T|Calcium nitrite (Ca(NO2)2)

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 390 °C
Density 2.23
Flash Point 110 °C
Color white-yellow hexagonal, hexane crystals, crystalline; hygroscopic
Odor Odorless
Form white-yellow hexagonal crystals
Water Solubility slightly soluble alcohol [MER06]; g/100g solution H2O: 38.3 (0°C), 43.0 (18.5°C), 71.2 (91°C); solid phase Ca(NO2)2 · 4H2O (0°C, 18.5°C), Ca(NO2)2 ·2H2O (91°C) [KRU93]
Refractive Index n 20/D 1.3946
Log P -2.52 at 20℃

Documentation

Safety & Handling Learn More

Danger
GHS03· Oxidizing GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS09· Environmental Hazard GHS08· Health Hazard

Hazard Statements

H272 May intensify fire; oxidizer
H301 Toxic if swallowed
H302 Harmful if swallowed
H318 Causes serious eye damage

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P220 Keep away from clothing and other combustible materials.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Trade & Regulatory

Storage Class 10 - Combustible liquids
WGK (Germany) 3
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