Amines REACH

Trisaminoethylamine

CAS Number
4097-89-6
EC Number
223-857-4
Abbreviation
TREN

What is Trisaminoethylamine?

Trisaminoethylamine (CAS 4097-89-6), commercially known as TREN, is a tetradentate triamine.

Where is Trisaminoethylamine used?

  • Coatings and adhesives: curing agent and cross-linker for epoxy systems
  • Water treatment: chelating agent that sequesters heavy metal ions
  • Polymer manufacturing: ligand in atom transfer radical polymerization (ATRP)
  • Lubricants and metalworking fluids: metal-complexing capacity
  • Its four nitrogen donor sites chelate metal ions and initiate controlled polymerization reactions.

Good to know: Buyers for sensitive polymer or coordination chemistry applications should confirm purity specifications directly with the supplier.

Commercial specifications

  • Purity typically 96–99% depending on application tier

Other Names (Synonyms)

N',n'-bis(2-aminoethyl)ethane-1,2-diamine|Tris(2-aminoethyl)amine|TREN

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What are the physical properties of Trisaminoethylamine?

Melting Point -16 °C
Boiling Point 265 °C
Density 0.976 g/mL at 20 °C(lit.)
Flash Point >230 °F
Appearance Colorless liquid
Color Clear yellow
Form saline suspension
Water Solubility Miscible with water.
Vapor Pressure 0.02 mm Hg ( 20 °C)
Refractive Index n 20/D 1.497(lit.)

How is Trisaminoethylamine classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H301 Toxic if swallowed
H302 Harmful if swallowed
H310 Fatal in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H370 Causes damage to organs

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Which trade and regulatory codes apply to Trisaminoethylamine?

HS Code 29211990
UN Number 2922
ADR Class 8
Packing Group II
WGK (Germany) 3
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