Amines REACH

Trisaminoethylamine

CAS Number
4097-89-6
EC Number
223-857-4
Chemical Formula
C6H18N4
Molecular Weight
146.23 g/mol
Abbreviation
TREN

Description

Trisaminoethylamine (CAS 4097-89-6), commercially known as TREN, is a tetradentate triamine used across polymer chemistry, metal treatment, and specialty formulation. Its four nitrogen donor sites make it effective for chelating metal ions and initiating controlled polymerization reactions in various industrial and laboratory settings.

In coatings and adhesives, TREN functions as a curing agent and cross-linker for epoxy systems, contributing to network density and adhesion performance in demanding industrial formulations. Water treatment operations use it as a chelating agent to sequester heavy metal ions, preventing scale formation and equipment fouling in process water circuits during operation.

In polymer manufacturing, TREN serves as a ligand in atom transfer radical polymerization (ATRP), enabling precise molecular weight control in specialty plastics and elastomers. Lubricant and metalworking fluid formulators incorporate it for its metal-complexing capacity, helping to stabilize formulations and protect metal surfaces under high-load conditions.

Trisaminoethylamine is supplied as a liquid. Technical grade is the standard commercial offering, with purity levels typically specified at 96–99% depending on the application tier. Buyers sourcing for sensitive polymer or coordination chemistry applications should confirm purity specifications directly with the supplier to ensure the material meets requirements.

Other Names (Synonyms)

N',n'-bis(2-aminoethyl)ethane-1,2-diamine|Tris(2-aminoethyl)amine|TREN

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
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Physical Properties

Melting Point -16 °C
Boiling Point 265 °C
Density 0.976 g/mL at 20 °C(lit.)
Flash Point >230 °F
Appearance Colorless liquid
Color Clear yellow
Form saline suspension
Water Solubility Miscible with water.
Vapor Pressure 0.02 mm Hg ( 20 °C)
Refractive Index n 20/D 1.497(lit.)

Documentation

Safety & Handling Learn More

Danger
GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H301 Toxic if swallowed
H302 Harmful if swallowed
H310 Fatal in contact with skin
H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H370 Causes damage to organs

Precautionary Statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Trade & Regulatory

HS Code 29211990
UN Number 2922
ADR Class 8
Packing Group II
WGK (Germany) 3
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