Caprolactone

CAS Number
502-44-3
EC Number
207-938-1
Abbreviation
CL

What is Caprolactone?

Caprolactone (CAS 502-44-3), also known as ε-caprolactone or CL, is a cyclic ester monomer used as a building block in polymer synthesis and as a reactive diluent in coating and resin systems.

Where is Caprolactone used?

  • Plastics and coatings: polymerized to polycaprolactone (PCL), a biodegradable thermoplastic for packaging films, adhesives and flexible molded parts
  • Printing inks and packaging: caprolactone-based polyols for flexibility and adhesion, also enhancing solvent resistance in polyurethane systems
  • Personal care: reactive ingredient in film-forming polymers and specialty esters for skin and hair formulations
  • Food: at trace levels it contributes creamy, coconut-like notes as a flavoring agent.

Good to know: Also known as ε-caprolactone or CL; FEMA code or E number where applicable. Not typically listed under FCC, USP, Ph. Eur., BP, EP or ACS.

Commercial specifications

  • Purity typically 99% or higher
  • Technical and polymer-grade specifications
  • Packaging from drums to isotanks

Other Names (Synonyms)

oxepan-2-one|hexanoic acid, epsilon-lactone|hexan-6-olide|epsilon-caprolactone monomer|epsilon-caprolactone|6-hydroxyhexanoic anhydride|6-hydroxyhexanoic acid, epsilon-lactone|6-hydroxyhexanoic acid lactone|CL

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What are the physical properties of Caprolactone?

Melting Point -18 °C
Boiling Point 253 °C
Density 1.030 g/cm³ (approx)
Flash Point 229 °F
Appearance clear liquid
Color Clear colorless, yellowing on aging
Form Liquid
Water Solubility >1000 MG/L (20 ºC)
Vapor Pressure 0.01 mm Hg ( 20 °C)
Refractive Index n 20/D 1.463(lit.)
Log P 0.32 at 20℃

How is Caprolactone classified and handled safely? Learn More

Warning
GHS07· Irritant

Hazard Statements

H319 Causes serious eye irritation

Precautionary Statements

P280 Wear protective gloves/protective clothing/eye protection/face protection.
P264+P265 Wash … thoroughly after handling.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Which trade and regulatory codes apply to Caprolactone?

HS Code 29322090
WGK (Germany) 2
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