Tetraethyl silicate

CAS Number
78-10-4
EC Number
201-083-8
Abbreviation
TEOS

What is Tetraethyl silicate?

Tetraethyl silicate (CAS 78-10-4), also known as TEOS or ethyl silicate, is a silicon alkoxide used as a reactive binder, crosslinker and silica precursor.

Where is Tetraethyl silicate used?

  • Coatings: silicate binder in zinc-rich and inorganic coatings
  • Construction: consolidates porous stone, concrete and masonry by penetrating the substrate
  • Adhesives and sealants: crosslinking agent for thermal stability
  • On hydrolysis it deposits amorphous silica, enabling surface treatments, protective coatings and ceramic structures without high-temperature sintering.
  • Used in aerogel production.
  • Largely used as a silicon source in the synthesis of silicon oxide for various optoelectronic applications.
  • Used as a crosslinking agent for silicone polymers.

Good to know: Ethyl Silicate 40 offers higher silica content for specialised coating applications. Standard purity grades range from technical to high-purity electronic grade for semiconductor use.

Formulation notes

  • Reacts with acids, water and oxidants.
  • Slowly hydrolyzes to silicon dioxide and ethanol upon contact with ambient moisture.
  • If a bubbler is used, the carrier gas must be moisture-free; otherwise polymerized products slowly accumulate in the reservoir, causing a decrease in vapor pressure and a shift in process characteristics.

Typical specification

  • Color scale ≤20 APHA.
  • SiO2 content 28% to 28.8%.

Regulatory status

  • Assigned UN number 1292 for transport.
  • UN classification: hazard class 3, packing group III.
  • Classified as causing serious eye irritation (H319).
  • EU OEL: 44 mg/m³, 5 ppm as TWA.

Storage, packaging and handling

  • Should be kept away from moisture.
  • Store fireproof, separated from acids and oxidants, cool, dry, and in a well-ventilated place.

Frequently asked questions about Tetraethyl silicate

What is the EU CLP harmonized classification index number for tetraethyl silicate?
The EU CLP harmonized classification index number is 014-005-00-0.
Which commercial grade of tetraethyl silicate is available at 99% purity?
Tetraethyl silicate is available as T 1400 (OTTO) with 99% purity, CAS 78-10-4.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

tetraethyl orthosilicate|ethyl silicate|ethyl orthosilicate|TEOS|Dynasil A|Silicon ethoxide|Silicon tetraethoxide|Silikan L

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What are the physical properties of Tetraethyl silicate?

Melting Point -82.5 °C
Boiling Point 168.8 °C @ Press: 760 Torr
Density 0.933 g/cm³ @ Temp: 20 °C
Flash Point 116 °F
Appearance Ethyl silicate is a colorless, flammable liquid with a sharp odor detectable @ 85 ppm
Color Colorless
Form Liquid
Water Solubility Hydrolysis
Vapor Pressure <1 mm Hg ( 20 °C)
Refractive Index n 20/D 1.382(lit.)
pH 7 (20°C)

How is Tetraethyl silicate classified and handled safely? Learn More

Warning
GHS02· Flammable GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H226 Flammable liquid and vapor
H315 Causes skin irritation
H319 Causes serious eye irritation
H320 Causes eye irritation

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.

Which trade and regulatory codes apply to Tetraethyl silicate?

HS Code 29209090
UN Number 1292
ADR Class 3
Packing Group III
Storage Class 3 - Flammable liquids
WGK (Germany) 1
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