Amines REACH

2-chloroaniline

CAS Number
95-51-2
EC Number
202-426-4

What is 2-chloroaniline?

2-Chloroaniline (CAS 95-51-2), also known as o-Chloroaniline, is an aromatic amine intermediate. Also marketed as o-Chloroaniline.

Where is 2-chloroaniline used?

  • Dye manufacturing: building block for azo dyes and pigments
  • Textile and printing: precursor in azo dye synthesis for colorants on fabric, paper and packaging
  • Pharmaceutical production: synthesis of active intermediates, with ortho-chloro substitution directing reaction pathways during API construction
  • Polymer and rubber processing: curing agent and cross-linker for elastomeric and plastic components
  • Agrochemical synthesis: starting material for herbicides and pesticides, where chlorinated aniline derivatives define biological activity
  • It is a liquid at ambient conditions.

Commercial specifications

  • Technical grade for industrial synthesis; higher-purity specifications offered
  • Packaging: drums to IBC containers, for laboratory-scale procurement and bulk industrial supply

Other Names (Synonyms)

o-Chloroaniline|1-Amino-2-chlorobenzene|2-Chlorophenylamine|Fast Yellow GC Base|Benzenamine, 2-chloro-|o-Aminochlorobenzene|Aniline, o-chloro-|o-Chloroaminobenzene

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What are the physical properties of 2-chloroaniline?

Melting Point -14 °C
Boiling Point 208.84 °C
Density 1.2114 g/cm³ @ Temp: 22 °C
Flash Point 98 °C
Appearance clear pale yellow to brown liquid
Color Clear pale yellow to brown
Odor Characteristic odour
Form Liquid
Water Solubility 5.13 g/L (20 ºC)
Vapor Pressure 0.5 hPa (20 °C)
Refractive Index n 20/D 1.589
Log P 1.72 at 20℃ and pH6-8

How is 2-chloroaniline classified and handled safely? Learn More

Danger
GHS06· Toxic GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard

Hazard Statements

H301 Toxic if swallowed
H302 Harmful if swallowed
H311 Toxic in contact with skin
H319 Causes serious eye irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.

Which trade and regulatory codes apply to 2-chloroaniline?

HS Code 29214210
UN Number 2019
ADR Class 6.1
Packing Group II
Storage Class 6.1A - Combustible acute toxic Cat. 1 and 2 very toxic hazardous materials
WGK (Germany) 2
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