Diaminodiphenyl ether

CAS Number
101-80-4
EC Number
202-977-0
Chemical Formula
C12H12N2O
Molecular Weight
200.24 g/mol
Abbreviation
ODA

Description

Diaminodiphenyl ether (CAS 101-80-4), commonly abbreviated as ODA and also known commercially as 4,4'-oxydianiline, is an aromatic diamine monomer used in the synthesis of high-performance polymers. It functions as a reactive building block and curing agent in systems where thermal stability and mechanical durability are critical requirements. ODA is a primary monomer in the production of polyimide films and resins.

In these applications, it reacts with dianhydrides to deliver materials used in flexible electronics, aerospace components, and high-temperature insulation. In epoxy formulations, it acts as a curing agent to produce thermosets. These materials feature elevated glass transition temperatures suited for structural composites and printed circuit board laminates. Polyurethane and polyurea systems incorporate ODA to introduce aromatic chain segments.

This improves rigidity and heat resistance in foam and coating applications. Specialty colorant and pigment manufacturers also use it as an intermediate in synthesizing azo dyes and pigments for printing inks. Diaminodiphenyl ether is supplied as an off-white to light tan crystalline powder. Technical and high-purity grades are available, with purity specifications typically ranging from 98% to 99%+ for industrial use.

These specifications meet monomer-grade requirements for polyimide synthesis. Packaging is offered in kilogram-scale bags through to bulk quantities for industrial polymer producers and chemical manufacturers.

Other Names (Synonyms)

4,4’-oxydianiline|4-(4-aminophenoxy)aniline|4,4'-diaminodiphenyl ether|ODA

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 186-187 °C
Boiling Point >300 °C
Density 1.417 g/cm³
Flash Point 426 °F
Appearance 4,40′-Oxydianiline is a white crystalline solid, or a beige powder.
Color White
Form Solid
Water Solubility Insoluble. <0.01 g/100 mL at 15 ºC
Vapor Pressure 10 mm Hg ( 240 °C)
Refractive Index 1.6660 (estimate)
Log P 0.72 at 20℃

Documentation

Safety & Handling Learn More

Danger
GHS06· Toxic GHS08· Health Hazard GHS09· Environmental Hazard GHS07· Irritant

Hazard Statements

H301 Toxic if swallowed
H302 Harmful if swallowed
H311 Toxic in contact with skin
H317 May cause an allergic skin reaction

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.

Trade & Regulatory

HS Code 29222900
UN Number 3077
ADR Class 9
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 3
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