p-phenylenediamine
Description
p-Phenylenediamine (CAS 106-50-3), commonly abbreviated as PPD or p-Diaminobenzene, is an aromatic diamine used across polymer, textile, and cosmetic manufacturing. It functions primarily as a curing agent, dye intermediate, and antioxidant precursor in industrial formulations.
In rubber and polymer processing, PPD derivatives serve as antiozonants and antidegradants, extending the service life of tires, belts, and industrial rubber goods. The textile and leather industries rely on PPD as a key intermediate in the synthesis of azo dyes and sulfur dyes.
These applications enable deep, wash-resistant coloration on fiber substrates. In aramid fiber production, including high-performance materials like Kevlar, it acts as a monomer in polycondensation reactions. This contributes directly to tensile strength and flame resistance.
Hair dye formulations in personal care use PPD as an oxidative colorant intermediate. In these applications, it reacts with hydrogen peroxide to produce permanent color. This chemical is essential for achieving long-lasting results in professional cosmetic products.
p-Phenylenediamine is supplied as a crystalline solid, typically in flake or powder form. Technical grade is the standard offering for industrial polymer and dye applications. This ensures the material meets the necessary specifications for large-scale manufacturing.
Material is commonly packaged in sealed, nitrogen-purged containers to maintain quality during storage and transit. Proper handling and storage are critical to prevent oxidation and ensure the chemical stability of the product upon arrival at your facility.
Physical Properties
| Melting Point | 145-147 °C |
| Boiling Point | 267 °C |
| Density | 1.1 g/cm³ |
| Flash Point | 156 °C |
| Appearance | p-Phenylenediamines are white to slightly red crystalline solids. They have been described as gray “light brown” which may result from exposure to air. |
| Color | White, gray, or purple to brown |
| Form | Powder or Flakes |
| Water Solubility | 47 g/L (25 ºC) |
| Vapor Pressure | 1.08 mm Hg ( 100 °C) |
| Refractive Index | 1.6339 (estimate) |
| pH | 9 (50g/l, H2O, 20℃) |
| Log P | -0.84 at 20℃ |
Safety & Handling (Learn More)
Trade & Regulatory
| HS Code | 29215119 |
| UN Number | 1673 |
| ADR Class | 6.1 |
| Packing Group | III |
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
| WGK (Germany) | 3 |
Documentation
Other Names
pPDA|paraphenylene-diamine|p-Diaminobenzene|benzene-1,4-diamine|4-phenylenediamine|4-Aminoaniline|1,4-phenylenediamine|1,4-diaminobenzene|PPD
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