SoleChem

p-phenylenediamine

Pigments & Colorants Plastics & Polymers
CAS
106-50-3
EC
203-404-7
Mol. Weight
108.14 g/mol

Description

p-Phenylenediamine (CAS 106-50-3), commonly abbreviated as PPD or p-Diaminobenzene, is an aromatic diamine used across polymer, textile, and cosmetic manufacturing. It functions primarily as a curing agent, dye intermediate, and antioxidant precursor in industrial formulations.

In rubber and polymer processing, PPD derivatives serve as antiozonants and antidegradants, extending the service life of tires, belts, and industrial rubber goods. The textile and leather industries rely on PPD as a key intermediate in the synthesis of azo dyes and sulfur dyes.

These applications enable deep, wash-resistant coloration on fiber substrates. In aramid fiber production, including high-performance materials like Kevlar, it acts as a monomer in polycondensation reactions. This contributes directly to tensile strength and flame resistance.

Hair dye formulations in personal care use PPD as an oxidative colorant intermediate. In these applications, it reacts with hydrogen peroxide to produce permanent color. This chemical is essential for achieving long-lasting results in professional cosmetic products.

p-Phenylenediamine is supplied as a crystalline solid, typically in flake or powder form. Technical grade is the standard offering for industrial polymer and dye applications. This ensures the material meets the necessary specifications for large-scale manufacturing.

Material is commonly packaged in sealed, nitrogen-purged containers to maintain quality during storage and transit. Proper handling and storage are critical to prevent oxidation and ensure the chemical stability of the product upon arrival at your facility.

Contact us for supply of p-phenylenediamine

Request Quote

Physical Properties

Melting Point 145-147 °C
Boiling Point 267 °C
Density 1.1 g/cm³
Flash Point 156 °C
Appearance p-Phenylenediamines are white to slightly red crystalline solids. They have been described as gray “light brown” which may result from exposure to air.
Color White, gray, or purple to brown
Form Powder or Flakes
Water Solubility 47 g/L (25 ºC)
Vapor Pressure 1.08 mm Hg ( 100 °C)
Refractive Index 1.6339 (estimate)
pH 9 (50g/l, H2O, 20℃)
Log P -0.84 at 20℃

Safety & Handling (Learn More)

Danger GHS06 GHS09 GHS07 GHS08 GHS05
Hazard Statements
H301 Toxic if swallowed
H311 Toxic in contact with skin
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H318 Causes serious eye damage
H319 Causes serious eye irritation
H320 Causes eye irritation
H331 Toxic if inhaled
H333 May be harmful if inhaled
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H373 May causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled
Precautionary Statements
P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 In case of inadequate ventilation wear respiratory protection.
P316 Get emergency medical help immediately.
P317 Get emergency medical help.
P319 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P391 Collect spillage.
P403 Store in a well-ventilated place.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P316 Get emergency medical help immediately.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P317 Get emergency medical help.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P316 Get emergency medical help immediately.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P342+P316 Get emergency medical help immediately.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P362+P364 Take off contaminated clothing and wash it before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 29215119
UN Number 1673
ADR Class 6.1
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 3

Documentation

Other Names

pPDA|paraphenylene-diamine|p-Diaminobenzene|benzene-1,4-diamine|4-phenylenediamine|4-Aminoaniline|1,4-phenylenediamine|1,4-diaminobenzene|PPD

Related Products

Need a chemical? Get a quote within 24 hours.

Call Request Quote