Amines REACH

p-phenylenediamine

CAS Number
106-50-3
EC Number
203-404-7
Chemical Formula
C6H8N2
Molecular Weight
108.14 g/mol
Abbreviation
PPD

Description

p-Phenylenediamine (CAS 106-50-3), commonly abbreviated as PPD or p-Diaminobenzene, is an aromatic diamine used across polymer, textile, and cosmetic manufacturing. It functions primarily as a curing agent, dye intermediate, and antioxidant precursor in industrial formulations. In rubber and polymer processing, PPD derivatives serve as antiozonants and antidegradants, extending the service life of tires, belts, and industrial rubber goods. The textile and leather industries rely on PPD as a key intermediate in the synthesis of azo dyes and sulfur dyes.

These applications enable deep, wash-resistant coloration on fiber substrates. In aramid fiber production, including high-performance materials like Kevlar, it acts as a monomer in polycondensation reactions. This contributes directly to tensile strength and flame resistance. Hair dye formulations in personal care use PPD as an oxidative colorant intermediate. In these applications, it reacts with hydrogen peroxide to produce permanent color. This chemical is essential for achieving long-lasting results in professional cosmetic products.

p-Phenylenediamine is supplied as a crystalline solid, typically in flake or powder form. Technical grade is the standard offering for industrial polymer and dye applications. This ensures the material meets the necessary specifications for large-scale manufacturing. Material is commonly packaged in sealed, nitrogen-purged containers to maintain quality during storage and transit. Proper handling and storage are critical to prevent oxidation and ensure the chemical stability of the product upon arrival at your facility.

Other Names (Synonyms)

pPDA|paraphenylene-diamine|p-Diaminobenzene|benzene-1,4-diamine|4-phenylenediamine|4-Aminoaniline|1,4-phenylenediamine|1,4-diaminobenzene|PPD

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 145-147 °C
Boiling Point 267 °C
Density 1.1 g/cm³
Flash Point 156 °C
Appearance p-Phenylenediamines are white to slightly red crystalline solids. They have been described as gray “light brown” which may result from exposure to air.
Color White, gray, or purple to brown
Form Powder or Flakes
Water Solubility 47 g/L (25 ºC)
Vapor Pressure 1.08 mm Hg ( 100 °C)
Refractive Index 1.6339 (estimate)
pH 9 (50g/l, H2O, 20℃)
Log P -0.84 at 20℃

Documentation

Safety & Handling Learn More

Danger
GHS06· Toxic GHS09· Environmental Hazard GHS07· Irritant GHS08· Health Hazard GHS05· Corrosive

Hazard Statements

H301 Toxic if swallowed
H311 Toxic in contact with skin
H315 Causes skin irritation
H317 May cause an allergic skin reaction

Precautionary Statements

P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.

Trade & Regulatory

HS Code 29215119
UN Number 1673
ADR Class 6.1
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 3
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