SoleChem

4,4-Diaminodiphenylmethane

CAS
101-77-9
EC
202-974-4
Mol. Weight
198.26 g/mol

Description

4,4-Diaminodiphenylmethane (CAS 101-77-9), commercially known as MDA, is an aromatic diamine used as a curing agent and polymer building block across rubber, coatings, and adhesive manufacturing.

Its two reactive amine groups enable controlled cross-linking and chain extension in high-performance polymer systems. In polyurethane and epoxy formulations, MDA functions as a hardener.

This process produces cured systems with elevated thermal and mechanical resistance suitable for industrial coatings and structural adhesives. Rubber compounders use it as an antioxidant and cross-linking agent.

It is frequently utilized in tire components and elastomeric seals where long-term heat stability is required. In polyurea and polyamide synthesis, MDA serves as a diamine monomer.

This contributes to the backbone of engineering polymers used in films, fibers, and molded parts. Textile and leather processing operations also apply MDA-derived intermediates in dye chemistry.

In these applications, it acts as a precursor to azo colorants for fiber dyeing. MDA is supplied as a solid, typically off-white to tan flakes or pastilles, and in molten form for bulk delivery.

Technical grade is the standard commercial specification, with purity levels commonly at 99% or above. Packaging ranges from 25 kg bags to bulk containers depending on volume requirements.

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Physical Properties

Melting Point 91.5-92 °C
Boiling Point 398-399 °C @ Press: 768 Torr
Density 1.056 g/cm³ @ Temp: 100 °C
Flash Point 430 °F
Appearance 4,4’-Diaminodiphenylmethane is a pale yel- low crystalline solid (turns light brown on contact with air) with a faint amine-like odor.
Color White to Light yellow
Form neat
Water Solubility Slightly soluble. <0.1 g/100 mL at 19 ºC
Vapor Pressure 0Pa at 25℃
Refractive Index 1.5014 (estimate)
Log P 1.55 at 25℃

Safety & Handling (Learn More)

Danger GHS07 GHS08 GHS09 GHS06
Hazard Statements
H301 Toxic if swallowed
H302 Harmful if swallowed
H311 Toxic in contact with skin
H316 Causes mild skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H341 Suspected of causing genetic defects
H350 May cause cancer
H351 Suspected of causing cancer
H361 Suspected of damaging fertility or the unborn child
H370 Causes damage to organs
H372 Causes damage to organs through prolonged or repeated exposure
H373 May causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements
P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P316 Get emergency medical help immediately.
P318 IF exposed or concerned, get medical advice.
P319 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P316 Get emergency medical help immediately.
P301+P317 Get emergency medical help.
P302+P352 IF ON SKIN: Wash with plenty of water.
P308+P316 Get emergency medical help immediately.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P362+P364 Take off contaminated clothing and wash it before reuse.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 29215900
UN Number 2651
ADR Class 6.1
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 3

Documentation

Other Names

4-[(4-aminophenyl)methyl]aniline|4,4'-methylenedianiline|MDA

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