4,4-Diaminodiphenylmethane
Description
4,4-Diaminodiphenylmethane (CAS 101-77-9), commercially known as MDA, is an aromatic diamine used as a curing agent and polymer building block across rubber, coatings, and adhesive manufacturing.
Its two reactive amine groups enable controlled cross-linking and chain extension in high-performance polymer systems. In polyurethane and epoxy formulations, MDA functions as a hardener.
This process produces cured systems with elevated thermal and mechanical resistance suitable for industrial coatings and structural adhesives. Rubber compounders use it as an antioxidant and cross-linking agent.
It is frequently utilized in tire components and elastomeric seals where long-term heat stability is required. In polyurea and polyamide synthesis, MDA serves as a diamine monomer.
This contributes to the backbone of engineering polymers used in films, fibers, and molded parts. Textile and leather processing operations also apply MDA-derived intermediates in dye chemistry.
In these applications, it acts as a precursor to azo colorants for fiber dyeing. MDA is supplied as a solid, typically off-white to tan flakes or pastilles, and in molten form for bulk delivery.
Technical grade is the standard commercial specification, with purity levels commonly at 99% or above. Packaging ranges from 25 kg bags to bulk containers depending on volume requirements.
Physical Properties
| Melting Point | 91.5-92 °C |
| Boiling Point | 398-399 °C @ Press: 768 Torr |
| Density | 1.056 g/cm³ @ Temp: 100 °C |
| Flash Point | 430 °F |
| Appearance | 4,4’-Diaminodiphenylmethane is a pale yel- low crystalline solid (turns light brown on contact with air) with a faint amine-like odor. |
| Color | White to Light yellow |
| Form | neat |
| Water Solubility | Slightly soluble. <0.1 g/100 mL at 19 ºC |
| Vapor Pressure | 0Pa at 25℃ |
| Refractive Index | 1.5014 (estimate) |
| Log P | 1.55 at 25℃ |
Safety & Handling (Learn More)
Trade & Regulatory
| HS Code | 29215900 |
| UN Number | 2651 |
| ADR Class | 6.1 |
| Packing Group | III |
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
| WGK (Germany) | 3 |
Documentation
Other Names
4-[(4-aminophenyl)methyl]aniline|4,4'-methylenedianiline|MDA
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