Amines REACH

4,4-Diaminodiphenylmethane

CAS Number
101-77-9
EC Number
202-974-4
Chemical Formula
C13H14N2
Molecular Weight
198.26 g/mol
Abbreviation
MDA

Description

4,4-Diaminodiphenylmethane (CAS 101-77-9), commercially known as MDA, is an aromatic diamine used as a curing agent and polymer building block across rubber, coatings, and adhesive manufacturing. Its two reactive amine groups enable controlled cross-linking and chain extension in high-performance polymer systems. In polyurethane and epoxy formulations, MDA functions as a hardener.

This process produces cured systems with elevated thermal and mechanical resistance suitable for industrial coatings and structural adhesives. Rubber compounders use it as an antioxidant and cross-linking agent. It is frequently utilized in tire components and elastomeric seals where long-term heat stability is required. In polyurea and polyamide synthesis, MDA serves as a diamine monomer.

This contributes to the backbone of engineering polymers used in films, fibers, and molded parts. Textile and leather processing operations also apply MDA-derived intermediates in dye chemistry. In these applications, it acts as a precursor to azo colorants for fiber dyeing. MDA is supplied as a solid, typically off-white to tan flakes or pastilles, and in molten form for bulk delivery.

Technical grade is the standard commercial specification, with purity levels commonly at 99% or above. Packaging ranges from 25 kg bags to bulk containers depending on volume requirements.

Other Names (Synonyms)

4-[(4-aminophenyl)methyl]aniline|4,4'-methylenedianiline|MDA

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
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Physical Properties

Melting Point 91.5-92 °C
Boiling Point 398-399 °C @ Press: 768 Torr
Density 1.056 g/cm³ @ Temp: 100 °C
Flash Point 430 °F
Appearance 4,4’-Diaminodiphenylmethane is a pale yel- low crystalline solid (turns light brown on contact with air) with a faint amine-like odor.
Color White to Light yellow
Form neat
Water Solubility Slightly soluble. <0.1 g/100 mL at 19 ºC
Vapor Pressure 0Pa at 25℃
Refractive Index 1.5014 (estimate)
Log P 1.55 at 25℃

Documentation

Safety & Handling Learn More

Danger
GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard GHS06· Toxic

Hazard Statements

H301 Toxic if swallowed
H302 Harmful if swallowed
H311 Toxic in contact with skin
H316 Causes mild skin irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.

Trade & Regulatory

HS Code 29215900
UN Number 2651
ADR Class 6.1
Packing Group III
Storage Class 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany) 3
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