4,4'-methylenebis(2,6-di-tert-butylphenol)

CAS Number
118-82-1
EC Number
204-279-1

What is 4,4'-methylenebis(2,6-di-tert-butylphenol)?

4,4'-methylenebis(2,6-di-tert-butylphenol) (CAS 118-82-1) is a hindered phenolic antioxidant. Also marketed as Ionox 220 and Binox M; E702 in food-contact applications.

Where is 4,4'-methylenebis(2,6-di-tert-butylphenol) used?

  • Polymers, lubricants and elastomers: protection from oxidative degradation during processing and service life
  • Lubricants: oxidation inhibition in industrial oils and metalworking fluids, extending service intervals and protecting metal surfaces
  • Rubber and tire compounds: prevention of heat-induced degradation during vulcanization and in-service flexing
  • Coatings and adhesives: stabilisation of resin systems against discoloration and viscosity drift during storage and cure
  • In plastics processing it protects polyolefins and engineering resins during high-temperature extrusion and injection molding.

Good to know: Technical and food-contact grades exist; the food-contact designation matters for buyers sourcing into food-packaging, where high purity is required.

Commercial specifications

  • Packaging: fiber drums and bags; bulk quantities for industrial procurement

Other Names (Synonyms)

Ionox 220|Binox M|Antioxidant E 702|Ethyl 702|4,4'-Methylenebis(2,6-di-t-butylphenol)|MB 1 (Antioxidant)|Ionox 220 antioxidant|LZ-MB 1|E702

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What are the physical properties of 4,4'-methylenebis(2,6-di-tert-butylphenol)?

Melting Point 152.5-153 °C
Boiling Point 289 °C40 mm Hg(lit.)
Density 0.99 g/cm3 (20℃)
Flash Point 289°C/40mm
Color White
Form solid
Water Solubility 31.9ng/L at 20℃
Vapor Pressure 0Pa at 25℃
Refractive Index 1.4875 (estimate)
Log P 8.9 at 25℃

Which trade and regulatory codes apply to 4,4'-methylenebis(2,6-di-tert-butylphenol)?

HS Code 29072990
WGK (Germany) 1
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