Tetramethylthiuram Disulfide

CAS Number
137-26-8
EC Number
205-286-2
Chemical Formula
C6H12N2S4
Molecular Weight
240.4 g/mol
Abbreviation
TMTD

Description

Tetramethylthiuram Disulfide (CAS 137-26-8), commercially known as Thiram and abbreviated TMTD, is an organosulfur compound used as a rubber vulcanization accelerator, fungicide, and industrial biocide. It functions across rubber processing, crop protection, and preservation applications where sulfur-donor chemistry is required. In rubber and tire manufacturing, TMTD acts as a primary or secondary vulcanization accelerator.

This chemical enables efficient crosslinking at lower temperatures and improves aging resistance in finished rubber goods. In agriculture, Thiram is an active ingredient in seed treatment and foliar fungicide formulations. It protects crops against a broad spectrum of fungal pathogens including Botrytis and Fusarium species. Industrial formulators use it as a biocide in latex preservation and polymer stabilization for aqueous rubber dispersions.

The compound also functions as a catalyst precursor in certain specialty chemical syntheses where controlled sulfur donation is required. It is supplied as a white to off-white powder or as pre-dispersed granules. Standard grades include technical-grade material meeting rubber industry specifications, as well as agricultural-grade material conforming to FAO/WHO pesticide standards. Purity typically ranges from 95% to 98%+.

The material is available in masterbatch forms suited for rubber compounding to ensure uniform distribution. This versatility makes it a critical component for manufacturers requiring high-performance sulfur-donor chemistry.

Other Names (Synonyms)

dimethylcarbamothioylsulfanyl N,N-dimethylcarbamodithioate|Thiram|TMTD

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 155-156 °C
Boiling Point 129 °C @ Press: 20 Torr
Density 1.29 g/cm³ @ Temp: 20 °C
Flash Point 89°C
Appearance Thiram is a colorless to yellow, crystalline solid. Characteristic odor. Commercial pesticide products may be dyed blue.
Odor char. odor
Form solid
Water Solubility 16.5 mg/L (20 ºC)
Vapor Pressure 8 x 10 -6 mmHg at 20 °C (NIOSH, 1997)
Refractive Index 1.5500 (estimate)
Log P 1.730

Documentation

Safety & Handling Learn More

Warning
GHS07· Irritant GHS08· Health Hazard GHS09· Environmental Hazard GHS06· Toxic

Hazard Statements

H302 Harmful if swallowed
H315 Causes skin irritation
H316 Causes mild skin irritation
H317 May cause an allergic skin reaction

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Trade & Regulatory

HS Code 29303000
UN Number 2771
Storage Class 13 - Non Combustible Solids
WGK (Germany) 3
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