Tetramethylthiuram monosulfide

CAS Number
97-74-5
EC Number
202-605-7
Abbreviation
TMTM

What is Tetramethylthiuram monosulfide?

Tetramethylthiuram monosulfide (CAS 97-74-5), also marketed as TMTM or Unads, is an organosulfur accelerator used primarily in rubber vulcanization and crop protection formulations.

Where is Tetramethylthiuram monosulfide used?

  • Rubber compounding: primary or secondary accelerator
  • Natural and synthetic rubber goods: controlled cure rates in seals, hoses and molded components
  • Agricultural formulations: fungicide and seed treatment agent targeting soil-borne pathogens in cereal and vegetable crops
  • Polymer stabilization: antioxidant additive in plastic compounds for long-term thermal stability
  • In latex systems it contributes to prevulcanization control, giving formulators tighter command over gel formation and final product consistency.

Good to know: Unlike its disulfide counterpart, the monosulfide structure offers a distinct cure profile suited to specific processing requirements.

Commercial specifications

  • Purity confirmed by active content assay
  • Pre-dispersed masterbatch forms for dust-free handling

Other Names (Synonyms)

BIS(DIMETHYLTHIOCARBAMOYL) SULFIDE|Unads|TMTM|Mono-thiurad|Aceto TMTM|Thiuram MM|TMTMS|Thiodicarbonic diamide ([(H2N)C(S)]2S), N,N,N′,N′-tetramethyl-

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What are the physical properties of Tetramethylthiuram monosulfide?

Melting Point 109.5 °C
Boiling Point 260.9±23.0 °C(Predicted)
Density 1.37 g/cm³ @ Temp: 20 °C
Flash Point 156 °C
Appearance yellow powder
Color Yellow
Odor odorless
Form Powder
Water Solubility insoluble
Vapor Pressure 0.002Pa at 25℃
Refractive Index 1.4825 (estimate)
Log P 1.17 at 20℃

How is Tetramethylthiuram monosulfide classified and handled safely? Learn More

Warning
GHS07· Irritant GHS09· Environmental Hazard GHS08· Health Hazard

Hazard Statements

H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Which trade and regulatory codes apply to Tetramethylthiuram monosulfide?

HS Code 29303000
UN Number 3077
ADR Class 9
Packing Group III
Storage Class 11 - Combustible Solids
WGK (Germany) 3
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