SoleChem

Tetramethylthiuram monosulfide

CAS
97-74-5
EC
202-605-7
Mol. Weight
208.4 g/mol

Description

Tetramethylthiuram monosulfide (CAS 97-74-5), commercially known as TMTM or Unads, is an organosulfur accelerator used primarily in rubber vulcanization and crop protection formulations.

Unlike its disulfide counterpart, the monosulfide structure offers a distinct cure profile suited to specific processing requirements. In rubber compounding, it functions as a primary or secondary accelerator.

This chemical enables controlled cure rates in natural and synthetic rubber goods including seals, hoses, and molded components. It is also used in agricultural formulations as a fungicide and seed treatment agent.

The product targets soil-borne pathogens in cereal and vegetable crops. Polymer stabilization is another application where it acts as an antioxidant additive in plastic compounds for long-term thermal stability.

In latex systems, it contributes to prevulcanization control, giving formulators tighter command over gel formation and final product consistency. This ensures high performance in specialized manufacturing environments.

The material is supplied as a pale yellow to off-white powder, the standard physical form for rubber and agricultural end uses. Technical grade is the predominant commercial specification for industrial use.

Purity is typically confirmed by active content assay to meet industry requirements. Pre-dispersed masterbatch forms are available for rubber processing applications where dust-free handling is a plant requirement.

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Physical Properties

Melting Point 109.5 °C
Boiling Point 260.9±23.0 °C(Predicted)
Density 1.37 g/cm³ @ Temp: 20 °C
Flash Point 156 °C
Appearance yellow powder
Color Yellow
Odor odorless
Form Powder
Water Solubility insoluble
Vapor Pressure 0.002Pa at 25℃
Refractive Index 1.4825 (estimate)
Log P 1.17 at 20℃

Safety & Handling (Learn More)

Warning GHS07 GHS09 GHS08
Hazard Statements
H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H332 Harmful if inhaled
H341 Suspected of causing genetic defects
H373 May causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H411 Toxic to aquatic life with long lasting effects
H302+H332 Harmful if swallowed or if inhaled
Precautionary Statements
P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P317 Get emergency medical help.
P318 IF exposed or concerned, get medical advice.
P319 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … on this label).
P330 Rinse mouth.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P301+P317 Get emergency medical help.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 29303000
UN Number 3077
ADR Class 9
Packing Group III
Storage Class 11 - Combustible Solids
WGK (Germany) 3

Documentation

Other Names

BIS(DIMETHYLTHIOCARBAMOYL) SULFIDE|Unads|TMTM|Mono-thiurad|Aceto TMTM|Thiuram MM|TMTMS|Thiodicarbonic diamide ([(H2N)C(S)]2S), N,N,N′,N′-tetramethyl-

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