Tetramethylthiuram monosulfide

CAS Number
97-74-5
EC Number
202-605-7
Chemical Formula
C6H12N2S3
Molecular Weight
208.4 g/mol
Abbreviation
TMTM

Description

Tetramethylthiuram monosulfide (CAS 97-74-5), commercially known as TMTM or Unads, is an organosulfur accelerator used primarily in rubber vulcanization and crop protection formulations. Unlike its disulfide counterpart, the monosulfide structure offers a distinct cure profile suited to specific processing requirements. In rubber compounding, it functions as a primary or secondary accelerator.

This chemical enables controlled cure rates in natural and synthetic rubber goods including seals, hoses, and molded components. It is also used in agricultural formulations as a fungicide and seed treatment agent. The product targets soil-borne pathogens in cereal and vegetable crops. Polymer stabilization is another application where it acts as an antioxidant additive in plastic compounds for long-term thermal stability.

In latex systems, it contributes to prevulcanization control, giving formulators tighter command over gel formation and final product consistency. This ensures high performance in specialized manufacturing environments. The material is supplied as a pale yellow to off-white powder, the standard physical form for rubber and agricultural end uses. Technical grade is the predominant commercial specification for industrial use.

Purity is typically confirmed by active content assay to meet industry requirements. Pre-dispersed masterbatch forms are available for rubber processing applications where dust-free handling is a plant requirement.

Other Names (Synonyms)

BIS(DIMETHYLTHIOCARBAMOYL) SULFIDE|Unads|TMTM|Mono-thiurad|Aceto TMTM|Thiuram MM|TMTMS|Thiodicarbonic diamide ([(H2N)C(S)]2S), N,N,N′,N′-tetramethyl-

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 109.5 °C
Boiling Point 260.9±23.0 °C(Predicted)
Density 1.37 g/cm³ @ Temp: 20 °C
Flash Point 156 °C
Appearance yellow powder
Color Yellow
Odor odorless
Form Powder
Water Solubility insoluble
Vapor Pressure 0.002Pa at 25℃
Refractive Index 1.4825 (estimate)
Log P 1.17 at 20℃

Documentation

Safety & Handling Learn More

Warning
GHS07· Irritant GHS09· Environmental Hazard GHS08· Health Hazard

Hazard Statements

H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Trade & Regulatory

HS Code 29303000
UN Number 3077
ADR Class 9
Packing Group III
Storage Class 11 - Combustible Solids
WGK (Germany) 3
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