SoleChem

4,4'-dithiodimorpholine

Amines Rubber & Tire
CAS
103-34-4
EC
203-103-0
Mol. Weight
236.4 g/mol

Description

4,4'-Dithiodimorpholine (CAS 103-34-4), commonly known as DTDM or Morpholine disulfide, is a sulfur-donor curing agent used in rubber vulcanization. It releases active sulfur during processing to form cross-links within elastomer networks.

This chemical enables controlled cure without relying on elemental sulfur alone. In tire manufacturing, DTDM is used in efficient vulcanization (EV) and semi-EV systems to produce compounds with improved heat aging resistance.

It helps reduce reversion, which is critical for components like sidewalls and inner liners. Rubber goods producers use it in mechanical goods, belts, and hoses where long-term thermal stability under dynamic stress is a priority.

It functions effectively as a secondary curative alongside accelerators such as CBS or TBBS. This allows formulators to fine-tune crosslink density and polysulfide distribution for specific industrial requirements.

Accel R is a recognized trade designation under which this material is supplied for compounding applications. DTDM is supplied as an off-white to pale yellow powder or as pre-dispersed masterbatch forms.

These forms are suited for mixing line integration in large scale facilities. Technical and rubber-grade specifications are standard across the market, with purity typically confirmed by active sulfur content.

The melting point range is also a key indicator of quality for this material. Packaging is available in multi-kilogram bags through to bulk quantities for industrial compounders and chemical distributors.

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Physical Properties

Melting Point 125 °C
Boiling Point 371.7±52.0 °C(Predicted)
Density 1.36 g/cm³ @ Temp: 25 °C
Color White to Almost white
Form powder to crystaline
Water Solubility 215mg/L at 20.2℃
Vapor Pressure 0.004Pa at 25℃
Refractive Index 1.6300 (estimate)
Log P 2.67 at 22℃

Safety & Handling (Learn More)

Warning GHS07 GHS09
Hazard Statements
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P319 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … on this label).
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
P264+P265 Wash … thoroughly after handling.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P332+P317 Get emergency medical help.
P333+P317 Get emergency medical help.
P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code 2934.99.9001

Documentation

Other Names

Morpholine, 4,4'-dithiobis-|Morpholine disulfide|Accel R|4,4'-Dithiomorpholine|Morpholino disulfide|Dimorpholine disulfide|Dimorpholino disulfide|Deovulc M|DTDM

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