Amines REACH

4,4'-dithiodimorpholine

CAS Number
103-34-4
EC Number
203-103-0
Chemical Formula
C8H16N2O2S2
Molecular Weight
236.4 g/mol
Abbreviation
DTDM

Description

4,4'-Dithiodimorpholine (CAS 103-34-4), commonly known as DTDM or Morpholine disulfide, is a sulfur-donor curing agent used in rubber vulcanization. It releases active sulfur during processing to form cross-links within elastomer networks. This chemical enables controlled cure without relying on elemental sulfur alone. In tire manufacturing, DTDM is used in efficient vulcanization (EV) and semi-EV systems to produce compounds with improved heat aging resistance.

It helps reduce reversion, which is critical for components like sidewalls and inner liners. Rubber goods producers use it in mechanical goods, belts, and hoses where long-term thermal stability under dynamic stress is a priority. It functions effectively as a secondary curative alongside accelerators such as CBS or TBBS. This allows formulators to fine-tune crosslink density and polysulfide distribution for specific industrial requirements.

Accel R is a recognized trade designation under which this material is supplied for compounding applications. DTDM is supplied as an off-white to pale yellow powder or as pre-dispersed masterbatch forms. These forms are suited for mixing line integration in large scale facilities. Technical and rubber-grade specifications are standard across the market, with purity typically confirmed by active sulfur content.

The melting point range is also a key indicator of quality for this material. Packaging is available in multi-kilogram bags through to bulk quantities for industrial compounders and chemical distributors.

Other Names (Synonyms)

Morpholine, 4,4'-dithiobis-|Morpholine disulfide|Accel R|4,4'-Dithiomorpholine|Morpholino disulfide|Dimorpholine disulfide|Dimorpholino disulfide|Deovulc M|DTDM

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 125 °C
Boiling Point 371.7±52.0 °C(Predicted)
Density 1.36 g/cm³ @ Temp: 25 °C
Color White to Almost white
Form powder to crystaline
Water Solubility 215mg/L at 20.2℃
Vapor Pressure 0.004Pa at 25℃
Refractive Index 1.6300 (estimate)
Log P 2.67 at 22℃

Documentation

Safety & Handling Learn More

Warning
GHS07· Irritant GHS09· Environmental Hazard

Hazard Statements

H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.

Trade & Regulatory

HS Code 2934.99.9001
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