Ethyl acetate

CAS Number
141-78-6
EC Number
205-500-4
FEMA Number
FEMA 2414
Abbreviation
EtOAc

What is Ethyl acetate?

Ethyl acetate (CAS 141-78-6), or EtOAc, is a fast-evaporating ester solvent. E1504; FEMA 2414.

Where is Ethyl acetate used?

  • Printing: primary solvent for nitrocellulose and polyurethane-based inks in flexible packaging and gravure printing
  • Pharmaceuticals: API extraction, recrystallization and tablet coating
  • Food and beverage: flavoring agent contributing a fruity note to confectionery, baked goods and alcoholic beverages
  • Food processing: used in the decaffeination of tea and coffee.
  • Cosmetics: fast-drying carrier solvent in nail lacquers and polish removers
  • Vitamin E synthesis: employed as a solvent.
  • Analytical chemistry: used as a standard material and solvent for analytical reagents and in chromatography analysis.
  • Laboratory work: mixtures containing it are commonly used in column chromatography and extractions.
  • Its evaporation rate affects print quality and line speed.

Good to know: Food and beverage uses require precise dosing at controlled levels for flavor consistency. Grade selection depends on end-use regulatory requirements, particularly food contact and pharmaceutical applications.

Formulation notes

  • Attacks rubber and some types of plastic.
  • Not compatible with nitrates, strong alkalis or strong acids.

Typical specification

  • Water content: 0.0500% maximum.
  • Autoignition temperature: 427°C.

Regulatory status

  • Assigned UN number 1173 for transport.
  • EU CLP harmonised index number 607-022-00-5.
  • Classified under UN transport as Class 3 flammable liquid, packing group II.
  • TLV: 400 ppm as TWA.

Storage, packaging and handling

  • Sensitive to heat; may form explosive peroxides on prolonged storage.
  • Explosive limits in air: 2.0–12.8 vol%.
  • Store away from strong oxidants, strong bases and strong acids.
  • Supplied in barrels, tins and IBCs.
  • Bulk tankers are dedicated cleaned tankers with approximately 20 MT loads.

Frequently asked questions about Ethyl acetate

What are typical purity and impurity limits for commercial ethyl acetate?
Commercial / Industrial Grade is available with a minimum purity of 99.80%; acidity as acetic acid is 0.0100% maximum and benzene is not detected in the product.
Can ethyl acetate replace aromatic solvents in formulations?
It can substitute aromatic solvents such as toluene and is used for resin thinning.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

vinegar naphtha|ethyl ethanoate|ethyl ester of acetic acid|ethyl acetic ester|Acetyl ester|Acetidin|Acetic-acid-ethylester|acetic ether|EtOAc|E1504

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What are the physical properties of Ethyl acetate?

Melting Point -83 °C
Boiling Point 77 °C
Density 0.902 g/cm³ @ Temp: 20 °C
Flash Point 26 °F
Appearance Ethyl acetate is a colorless liquid. Pleasant, fruity odor.
Color APHA: ≤10
Odor Pleasant fruity odor detectable at 7 to 50 ppm (mean = 18 ppm)
Form Liquid
Water Solubility 80 g/L (20 ºC)
Vapor Pressure 73 mm Hg ( 20 °C)
Refractive Index n 20/D 1.3720(lit.)
Log P 0.68-0.73 at 20-25℃

How is Ethyl acetate classified and handled safely? Learn More

Danger
GHS02· Flammable GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H225 Highly Flammable liquid and vapor
H319 Causes serious eye irritation
H320 Causes eye irritation
H332 Harmful if inhaled

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.

Which trade and regulatory codes apply to Ethyl acetate?

HS Code 29153100
UN Number 1173
ADR Class 3
Packing Group II
Storage Class 3 - Flammable liquids
WGK (Germany) 1
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