Acetic acid

CAS Number
64-19-7
EC Number
200-580-7
E Number
E260
FEMA Number
FEMA 2006
Abbreviation
AcOH

What is Acetic acid?

Acetic acid (CAS 64-19-7), commercially recognized as E260, is the primary organic acid used in food, pharmaceutical, and industrial manufacturing.

Where is Acetic acid used?

  • Food and beverage: pH control, preservative and flavoring agent in condiments, pickles and sauces
  • Pharmaceutical: buffering agent, reagent or solvent in active ingredient synthesis; raw material for manufacturing pharmaceuticals such as acetylsalicylic acid (aspirin), synthetic caffeine, certain vitamins, and hormones.
  • Textile and leather: dye bath pH regulator for fiber uptake and fixation
  • Personal care: hair rinses and toners where controlled acidity affects cuticle conditioning and product stability
  • It functions as an acidulant, pH regulator, preservative and solvent carrier depending on the sector.
  • Used in the manufacture of acetic anhydride.
  • Raw material for manufacturing solvents such as ethyl acetate, isopropyl acetate, and butyl acetate.

Good to know: Glacial acetic acid, the concentrated and anhydrous form, is a distinct grade relevant to industrial and synthesis buyers.

Formulation notes

  • Glacial acetic acid will corrode metal.
  • Attacks some plastics, rubber, and coatings.

Typical specification

  • Glacial acetic acid solidifies below 16.7 °C (17 °C).
  • Glacial acetic acid is considered practically pure at 99.5% and above, with water as the main impurity.
  • Autoignition temperature of 485°C.
  • Possible impurities depend on the manufacturing process and can include acetaldehyde, acetic anhydride, formic acid, diacetyl, methyl acetate, ethyl acetoacetate, iron, mercury, iodine, bromine, and chlorides.

Regulatory status

  • UN number 2789 applies to acetic acid, glacial acetic acid, or acetic acid solutions containing more than 80% acid by weight.
  • Has the EU index number 607-002-00-6.
  • Classified under CLP as a flammable liquid and vapour (H226).
  • The harmonised CLP classification and labelling is mandatory.

Storage, packaging and handling

  • Reacts violently with strong oxidants, creating a fire and explosion hazard.
  • Must be stored away from food and feed, strong oxidants, strong acids, and strong bases.
  • Should be stored only in its original container, well closed, in a well-ventilated place.
  • Should be stored in an area without access to drains or sewers.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

methanecarboxylic acid|ethylic acid|ethoic acid|ethanoic acid|Vinegar acid|Acetic acid glacial|Glacial acetic acid|Acetasol|AcOH|E260

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What are the physical properties of Acetic acid?

Melting Point 16.6 °C
Boiling Point 117.9 °C
Density 1.0446 g/cm³ @ Temp: 25 °C
Flash Point 104 °F
Appearance Description: Acetic acid is a colorless liquid or crystals with a sour, vinegar-like odor. Pure compound is a solid below 17 C. Often used in an aqueous solution. Glacial acetic acid contains 99% acid.
Color colorless
Odor Strong, pungent, vinegar-like odor detectable at 0.2 to 1.0 ppm
Form Solution
Water Solubility miscible
Vapor Pressure 11.4 mm Hg ( 20 °C)
Refractive Index n 20/D 1.371(lit.)
pH 2.5 (50g/l, H2O, 20℃)
Log P -0.170

How is Acetic acid classified and handled safely? Learn More

Danger
GHS02· Flammable GHS05· Corrosive GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H226 Flammable liquid and vapor
H303 May be harmful if swallowed
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment.

Which trade and regulatory codes apply to Acetic acid?

HS Code 29152100
UN Number 1792
ADR Class 8
Packing Group II
Storage Class 3 - Flammable liquids
WGK (Germany) 3
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