Phosphoric acid

CAS Number
7664-38-2
EC Number
231-633-2
E Number
E338
FEMA Number
FEMA 2900

What is Phosphoric acid?

Phosphoric acid (CAS 7664-38-2), also known as orthophosphoric acid and designated E338 in food applications, is a mineral acid used across industrial, food, and pharmaceutical sectors.

Where is Phosphoric acid used?

  • Food and beverage: acidifies carbonated soft drinks and acts as a flavor modifier
  • Metal surface treatment: rust conversion and phosphate coating prior to painting or galvanizing
  • Water treatment: phosphate dosing for corrosion inhibition in distribution pipelines
  • Pharmaceutical and industrial cleaning formulations: pH adjustment and sequestrant
  • These formulations stabilize active ingredients against metal ion interference.
  • Cleaning of production equipment in the food industry.
  • Binders for refractory and ceramic materials.
  • Wastewater treatment.
  • pH adjustment of water in industrial processes such as boilers and cooling towers.

Good to know: FEMA 2902 recognition supports its use in flavoring systems. Food-grade material meets FCC and E338 specifications; pharmaceutical-grade supply meets USP and Ph. Eur. requirements.

Formulation notes

  • Reacts violently with bases.
  • The 75% concentration is more fluid and easier to pump and dose at room temperature than more concentrated grades.

Typical specification

  • Commercially available as aqueous solutions at various concentrations, most commonly 75%, 80%, and 85%.
  • The wet process can include an additional purification step to obtain technical or food grade acids.
  • The 85% commercial solution melts at 21°C and may solidify at low temperatures.

Regulatory status

  • For transport, classified under UN hazard class 8 with packing group III.
  • Solutions with <10% phosphoric acid are not classified under CLP.

Storage, packaging and handling

  • Reacts with metals to release flammable hydrogen gas.
  • Should be stored in a cool, dry, well-ventilated place away from direct sunlight, heat, ignition sources, and incompatible materials.
  • Should be stored in the original, labelled, shipping container, tightly closed and properly labelled.

Frequently asked questions about Phosphoric acid

Which materials should be avoided in contact with phosphoric acid?
Do not transfer into unlined steel containers or leave in contact with metal fittings because it can attack metals.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

white phosphoric acid|phosphoric(V) acid|orthophosphoric acid|naval jelly|H3PO4|E338|[PO(OH)3]|o-Phosphoric acid

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What are the physical properties of Phosphoric acid?

Melting Point 42.35 °C
Boiling Point 158 °C
Density 1.834 g/cm³ @ Temp: 18 °C
Appearance Phosphoric acid is a colorless, odorless, crystalline solid or a thick syrupy liquid. Physical state is strength and temperature dependent.
Color ≤10(APHA)
Odor Odorless
Form Solid or Viscous Liquid
Water Solubility MISCIBLE
Vapor Pressure 2.2 mm Hg ( 20 °C)
Refractive Index n 20/D 1.433
pH <0.5 (100g/l, H2O, 20℃)
Log P -2.15

How is Phosphoric acid classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant GHS06· Toxic GHS08· Health Hazard

Hazard Statements

H290 May be corrosive to metals
H302 Harmful if swallowed
H313 May be harmful in contact with skin
H314 Causes severe skin burns and eye damage

Precautionary Statements

P234 Keep only in original packaging.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.

Which trade and regulatory codes apply to Phosphoric acid?

HS Code 28092000
UN Number 3453
ADR Class 8
Packing Group III
Storage Class 8A - Combustible corrosive hazardous materials
WGK (Germany) 3
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