Citric acid monohydrate

CAS Number
5949-29-1
EC Number
691-328-9

What is Citric acid monohydrate?

Citric acid monohydrate (CAS 5949-29-1), designated E330 in food and beverage applications, is a crystalline organic acid produced with one molecule of water of crystallization.

Where is Citric acid monohydrate used?

  • Food and beverage: acidulant and preservative in soft drinks, confectionery and canned goods, controlling pH and inhibiting microbial growth
  • Pharmaceutical: buffer for oral solutions and effervescent tablets
  • Topical preparations: pH adjustment for stability and active ingredient compatibility
  • Personal care: pH adjuster and chelating agent in shampoos, skin creams and hair rinses, sequestering hard water minerals
  • Water treatment: removes scale deposits and chelates heavy metal ions in industrial cleaning
  • It acidifies and preserves products in food and beverage manufacturing.

Good to know: Technical grade is available for industrial and water treatment applications where pharmaceutical-level purity is not required.

Commercial specifications

  • Grades: FCC, USP, BP, Ph. Eur.

Other Names (Synonyms)

Citric acid hydrate|1,2,3-Propanetricarboxylic acid, 2-hydroxy-, monohydrate|2968PHW8QP|1,2,3-Propanetricarboxylic acid, 2-hydroxy-, hydrate (1:1)|Acidum citricum monohydrate|2-Hydroxy-1,2,3-propanetricarboxylic acid hydrate (1:1)|2-Hydroxy-1,2,3-propanetricarboxylic acid monohydrate|Monohydrate Citric Acid|E330

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What are the physical properties of Citric acid monohydrate?

Melting Point 135 °C
Boiling Point 56 °C760 mm Hg(lit.)
Density 1.5 g/cm³
Flash Point 1 °F
Appearance white crystals or powder
Color White
Odor Typical, practically odorless
Form Solid
Water Solubility 1630 g/L (20 ºC)
Vapor Pressure 184 mm Hg ( 20 °C)
Refractive Index n 20/D 1.359(lit.)
pH 1.85 (50g/l, H2O, 25℃)

How is Citric acid monohydrate classified and handled safely? Learn More

Warning
GHS07· Irritant

Hazard Statements

H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Which trade and regulatory codes apply to Citric acid monohydrate?

HS Code 29181400
UN Number 1090
ADR Class 3
Packing Group II
Storage Class 11 - Combustible Solids
WGK (Germany) 1
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