Calcium citrate

CAS Number
813-94-5
EC Number
212-391-7
E Number
E333

What is Calcium citrate?

Calcium citrate (CAS 813-94-5), also marketed as E333iii, is the calcium salt of citric acid used in food, pharmaceutical, and personal care manufacturing.

Where is Calcium citrate used?

  • Food and beverage: pH stabiliser in processed products and sequestrant preventing metal-catalysed oxidation in canned goods and beverages
  • Pharmaceuticals: bioavailable calcium source in dietary supplement tablets and capsules
  • Personal care: pH buffer in topical formulations and chelator of trace metals that degrade active ingredients
  • Fruit and vegetable processing: firming agent maintaining texture in canned and frozen products
  • It also functions as a buffering agent, chelating agent, and mineral supplement source.

Good to know: Its absorption profile suits formulations targeting populations with low gastric acid levels. Recognised grades include FCC, USP, and Ph. Eur.

Commercial specifications

  • Anhydrous grade is standard for dry supplement and food applications requiring high purity and stability
  • Bulk quantities in fiber drums or multi-wall bags

Other Names (Synonyms)

tricalcium citrate|calcium citrate anhydrous|Tricalcium dicitrate|Citrical|Calcium citrate, tribasic|Citracal|Tribasic calcium citrate|1,2,3-Propanetricarboxylic acid, 2-hydroxy-, calcium salt (2:3)|E333iii

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What are the physical properties of Calcium citrate?

Appearance white powder or white to colourless crystals
Odor Odorless
Log P -1.721 (est)

Which trade and regulatory codes apply to Calcium citrate?

WGK (Germany) 1
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