Formic acid

CAS Number
64-18-6
EC Number
200-579-1
Chemical Formula
CH2O2
Molecular Weight
46.025 g/mol
E Number
E232
FEMA Number
FEMA 2487

Description

Formic acid (CAS 64-18-6), also known by its E-number E236, is the simplest carboxylic acid and a commercially significant organic acid used across industrial, agricultural, and food applications. It functions as a pH regulator, preservative, and processing aid depending on the sector, and its reducing character makes it useful in catalytic and chemical synthesis contexts.

In leather and textile processing, formic acid controls bath pH during dyeing and tanning, directly affecting color uptake and hide quality. This ensures consistent results in large-scale manufacturing. Silage preservation and animal feed acidification represent major agricultural volume, where it inhibits microbial spoilage and extends shelf life without requiring heat treatment or complex additives.

Food and beverage producers use it as an approved acidulant and preservative, particularly in baked goods, beverages, and dairy applications. It is a versatile tool for maintaining product stability. In pharmaceuticals and water treatment, it serves as a pH-adjusting agent and intermediate in synthesis. Its chelating capacity supports scale and metal ion control in process water systems.

Formic acid is supplied as an aqueous liquid, with 85% and 94% concentrations being the most commercially standard. Food-grade material is available to FCC and E236 specifications. Technical-grade product covers industrial and agricultural end uses where high purity is less critical. Bulk supply is typical in IBC containers and road tankers for efficient logistics.

Other Names (Synonyms)

methoic acid|methanoic acid|hydrogen carboxylic acid|HCOOH|HCO2H|formylic acid|aminic acid|Bilorin|E236

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 8.4 °C
Boiling Point 100.5 °C
Density 1.220 g/cm³ @ Temp: 20 °C
Flash Point 133 °F
Appearance Colorless, fuming liquid; penetrating odor. strong reducing agent. Soluble in water, alcohol, and ether. Combustible.
Color APHA: ≤15
Odor at 0.10 % in water. pungent vinegar formyl
Form Liquid
Water Solubility MISCIBLE
Vapor Pressure 52 mm Hg ( 37 °C)
Refractive Index n 20/D 1.377
pH 2.2 (10g/l, H2O, 20℃)
Log P -0.540

Documentation

Safety & Handling Learn More

Danger
GHS02· Flammable GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H226 Flammable liquid and vapor
H290 May be corrosive to metals
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P234 Keep only in original packaging.

Trade & Regulatory

HS Code 29151100
UN Number 1198
ADR Class 3
Packing Group III
Storage Class 3 - Flammable liquids
WGK (Germany) 2
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