Formic acid

CAS Number
64-18-6
EC Number
200-579-1
E Number
E232
FEMA Number
FEMA 2487

What is Formic acid?

Formic acid (CAS 64-18-6), also known by its E-number E236, is the simplest carboxylic acid and a commercially significant organic acid.

Where is Formic acid used?

  • Leather and textile processing: controls bath pH during dyeing and tanning, affecting colour uptake and hide quality
  • Agriculture: silage preservation and animal feed acidification inhibit microbial spoilage and extend shelf life
  • Food and beverage: approved acidulant and preservative in baked goods, beverages and dairy
  • Pharmaceuticals and water treatment: pH-adjusting agent and synthesis intermediate
  • Its chelating capacity supports scale and metal ion control in process water systems.
  • Industrial cleaning: used in industrial cleaners and for paint stripping.
  • Rubber industry: used particularly for latex coagulation and various production processes, contributing to maintaining production quality.

Good to know: Technical-grade product covers industrial and agricultural end uses where high purity is less critical.

Formulation notes

  • Reacts with amines and attacks many plastics and metals.

Typical specification

  • Miscible with water and alcohol solvents.
  • Color of 10 max. Pt-Co.
  • Chloride content of 0.002% max. or 0.0005% max. as Cl.

Regulatory status

  • For transport, classified as UN Class 8 (corrosive) with packing group II.

Storage, packaging and handling

  • Reacts violently with strong oxidants, isocyanates and strong bases, creating fire and explosion hazards and toxic gas.
  • Decomposes on heating, producing toxic and flammable gases and formaldehyde.
  • Formic acid 85% should be stored in closed, corrosion-resistant containers in cool, ventilated places away from oxidizing agents.
  • Available in 1200 kg IBC tanks.

Frequently asked questions about Formic acid

Does formic acid act only as an acidifying agent?
No, formic acid acts as both an acidifying and a reducing agent.

Technical content is compiled and updated by the SoleChem product team from public technical sources; the certificate of analysis (COA) governs product-specific specifications.

Other Names (Synonyms)

methoic acid|methanoic acid|hydrogen carboxylic acid|HCOOH|HCO2H|formylic acid|aminic acid|Bilorin|E236

Contact us for supply of Formic acid

Request Quote

What are the physical properties of Formic acid?

Melting Point 8.4 °C
Boiling Point 100.5 °C
Density 1.220 g/cm³ @ Temp: 20 °C
Flash Point 133 °F
Appearance Colorless, fuming liquid; penetrating odor. strong reducing agent. Soluble in water, alcohol, and ether. Combustible.
Color APHA: ≤15
Odor at 0.10 % in water. pungent vinegar formyl
Form Liquid
Water Solubility MISCIBLE
Vapor Pressure 52 mm Hg ( 37 °C)
Refractive Index n 20/D 1.377
pH 2.2 (10g/l, H2O, 20℃)
Log P -0.540

How is Formic acid classified and handled safely? Learn More

Danger
GHS02· Flammable GHS05· Corrosive GHS06· Toxic GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H226 Flammable liquid and vapor
H290 May be corrosive to metals
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage

Precautionary Statements

P203 Obtain, consult and follow expert instructions for use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P234 Keep only in original packaging.

Which trade and regulatory codes apply to Formic acid?

HS Code 29151100
UN Number 1198
ADR Class 3
Packing Group III
Storage Class 3 - Flammable liquids
WGK (Germany) 2
Call Request Quote