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Potassium polysulfide

Salts & Minerals Water Treatment
CAS
37199-66-9
EC
253-390-1
Mol. Weight
73.18 g/mol

Description

Potassium polysulfide (CAS 37199-66-9) is an inorganic sulfur-potassium salt used industrially as a biocide and chemical treatment agent across water management, mining, and agricultural applications.

Its sulfide chemistry enables targeted precipitation, microbial control, and soil amendment functions that drive demand across multiple regulated sectors. In water treatment, it precipitates heavy metals from industrial effluent streams.

This supports compliance with discharge limits for lead, mercury, and cadmium. Mining operations use it for selective sulfidization of oxidized copper and gold ores ahead of flotation, improving mineral recovery from refractory feed materials.

In agriculture, it functions as a registered pesticide for controlling fungal pathogens and mite populations on crops. It is typically applied as a foliar spray in approved programs to ensure crop health and yield.

Industrial pH buffering applications also employ it where alkaline sulfide chemistry is needed to condition process streams before downstream treatment. Potassium polysulfide is supplied as an aqueous solution for ease of use.

Concentration and polysulfide chain length vary by grade and intended use. Agricultural and pesticide-grade material is formulated to meet EPA registration requirements, while technical-grade solution is available for mining.

Water treatment procurement also utilizes technical-grade solutions for large-scale operations. Packaging typically ranges from drums to intermediate bulk containers (IBCs) depending on specific volume requirements.

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Physical Properties

Melting Point 400 °C
Flash Point >200 °C
Appearance Ochre to brown lumps
Form solid

Safety & Handling (Learn More)

Danger GHS05 GHS09 GHS02
Hazard Statements
H314 Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
H400 Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]

Trade & Regulatory

HS Code 28309085
Storage Class 4.2 - Pyrophoric and self-heating hazardous materials
WGK (Germany) 2

Documentation

Other Names

Caswell No. 701|EPA Pesticide Chemical Code 076703|RefChem:175584|potassium;sulfane|Potassium sulfide (K2(Sx))

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