Phosphorus pentasulfide
Description
Phosphorus pentasulfide (CAS 1314-80-3), also known as P4S10 and phosphorus persulfide, is a reactive inorganic compound used primarily as a chemical intermediate in the synthesis of organosulfur compounds.
Its core industrial value lies in its ability to introduce both phosphorus and sulfur into organic molecules, making it a critical building block across agrochemical, lubricant additive, and mineral processing chemistries.
In lubricant and metalworking fluid formulations, it serves as a precursor to zinc dialkyldithiophosphate (ZDDP) and related antiwear and extreme-pressure additives for high-performance applications.
Agrochemical producers use it to manufacture dithiophosphate-based pesticides and insecticides, where controlled reactivity with alcohols and amines drives active ingredient synthesis for crop protection.
In mining and flotation chemistry, dithiophosphate collectors derived from P4S10 improve selective mineral separation in sulfide ore processing, enhancing the efficiency of metal extraction operations.
It also functions as a catalyst or reagent in specialty organic synthesis, including the production of pharmaceuticals and flame retardants, providing versatile chemical pathways for manufacturers.
Phosphorus pentasulfide is supplied as a yellow-green powder or fused lump form, typically packaged under inert atmosphere due to its high moisture sensitivity and reactive nature.
Technical and industrial grades are the standard commercial offering, with purity specifications commonly ranging from 98% to 100% P4S10 content. Bulk supply in drums or IBCs is standard for industrial buyers.
Physical Properties
| Melting Point | 286-290 °C |
| Boiling Point | 513-515 °C |
| Density | 2.062 g/cm³ |
| Appearance | Phosphorus pentasulfide is a greenish-gray to yellow, crystalline solid with an odor of rotten eggs. The Odor Threshold is 0.005 ppm |
| Color | Yellow to green |
| Odor | rotten egg odor |
| Form | Powder |
| Water Solubility | reacts |
| pH | 1 (10g/l, H2O, 20℃) |
Safety & Handling (Learn More)
Trade & Regulatory
| HS Code | 28139000 |
| UN Number | 1340 |
| ADR Class | 4.3 |
| Packing Group | II |
| Storage Class | 4.3 - Hazardous materials, which set free flammable gases upon contact with water |
| WGK (Germany) | 3 |
Documentation
Other Names
sulfur phosphide|phosphorus persulfide|P4S10|phosphorus sulfide|Tetraphosphorus decasulfide|Phosphoric sulfide|Diphosphorus pentasulfide|Thiophosphoric anhydride
Related Products
Need a chemical? Get a quote within 24 hours.