Potassium peroxymonosulfate

CAS Number
37222-66-5
EC Number
609-357-2
Abbreviation
KMPS

What is Potassium peroxymonosulfate?

Potassium peroxymonosulfate (CAS 37222-66-5), also known as potassium caroate or KMPS, is an active oxygen-releasing compound supplied commercially as a triple salt.

Where is Potassium peroxymonosulfate used?

  • Water treatment: shock oxidizer for swimming pools and aquaculture systems, breaking down organic contaminants
  • Biofilm control without raising chlorine levels
  • Personal care: active oxidant in hair color activators and denture cleaning tablets
  • Pulp and paper: bleaching and brightness retention in chlorine-free processing lines
  • Textile and leather finishing: pre-treatment oxidant to improve dye uptake and surface uniformity
  • It functions as a non-chlorine oxidizer in disinfection, bleaching, and surface activation.

Commercial specifications

  • Active oxygen content typically around 4.5%
  • Industrial and specialty formulation grades for personal care and water treatment

Other Names (Synonyms)

potassium caroate|Potassium peroxymonosulfate sulfate (2KHSO5.KHSO4.K2SO4)|Potassium monopersulfate|KMPS

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What are the physical properties of Potassium peroxymonosulfate?

Melting Point >70°C (dec.)
Density 1.12-1.20
Appearance white granular crystalline powder
Color White
Form Granular Crystalline Powder
Water Solubility 250 G/L (20 ºC)
pH pH:1.4~1.9(50g/l, 25℃)

Which trade and regulatory codes apply to Potassium peroxymonosulfate?

HS Code 28334000
UN Number 3260
ADR Class 8
Packing Group II
WGK (Germany) 1
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