Ammonium persulfate

CAS Number
7727-54-0
EC Number
231-786-5
Chemical Formula
H3N.1/2H2O8S2
Molecular Weight
228.21 g/mol
Abbreviation
APS

Description

Ammonium persulfate (CAS 7727-54-0), also known as APS and approved as E923, is a strong inorganic oxidizer used across polymer manufacturing, electronics processing, and surface treatment industries. Its high oxidizing potential makes it effective as a polymerization initiator, bleaching agent, and etchant across a broad range of industrial processes. In plastics and polymer production, APS initiates free-radical polymerization.

It is used for acrylic, styrene, and vinyl-based monomers, forming the backbone of emulsion and suspension polymerization systems. Printed circuit board manufacturers rely on it as a microetchant to clean copper surfaces. This process ensures consistent adhesion in multilayer board fabrication by roughening surfaces before plating. Textile and paper processors use it to bleach natural fibers and pulp, removing color bodies effectively.

The chemical works without degrading substrate integrity during the bleaching process. In water treatment, it functions as an oxidizing agent to break down organic contaminants and support advanced oxidation processes. Ammonium persulfate is supplied as a white crystalline powder or granules. Standard commercial grades include technical grade for industrial applications and food-grade material meeting specific regulatory requirements.

Purity levels of 98% and above are typical for electronics and polymer-grade supply. The material is handled according to strict safety protocols due to its strong oxidizing properties and reactivity in various environments.

Other Names (Synonyms)

Ammonium peroxydisulfate|Diammonium peroxydisulfate|Diammonium peroxydisulphate|Diammonium persulfate|Ammonium persulphate|Persulfate d'ammonium|22QF6L357F|Peroxydisulfuric acid ([(HO)S(O)2]2O2), ammonium salt (1:2)|APS|E923

Key Technical Features

  • High Purity Grade standard
  • Consistent Batch Quality
  • Full Regulatory & REACH Support
  • Global Logistics Network enabled

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Physical Properties

Melting Point 187 °C (monoclinic crystal) (decomp)
Density 1.9 g/cm³
Appearance Ammonium persulfate is a colorless or white crystalline solid.
Color White to yellow
Odor Odorless
Form powder
Water Solubility 582 g/L (20 ºC) decomposes
Vapor Pressure 0Pa at 25℃
Refractive Index 1.50
pH 1.0-2.5 (25℃, 1M in H2O)
Log P -1 at 20℃

Documentation

Safety & Handling Learn More

Danger
GHS03· Oxidizing GHS07· Irritant GHS08· Health Hazard

Hazard Statements

H272 May intensify fire; oxidizer
H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P220 Keep away from clothing and other combustible materials.
P233 Keep container tightly closed.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.

Trade & Regulatory

HS Code 28334000
UN Number 1444
ADR Class 5.1
Packing Group III
Storage Class 5.1B - Oxidizing hazardous materials
WGK (Germany) 1
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