Benzoyl peroxide

CAS Number
94-36-0
EC Number
202-327-6
Abbreviation
BPO

What is Benzoyl peroxide?

Benzoyl peroxide (CAS 94-36-0), also known as BPO and approved as E928 in food applications, is an organic peroxide used as a free-radical initiator, bleaching agent, and curing catalyst.

Where is Benzoyl peroxide used?

  • Plastics and rubber: free-radical polymerization initiator
  • Resins, silicones and elastomers: cross-linking agent influencing cure speed and material properties
  • Food treatment: flour bleaching agent accelerating natural whitening of wheat flour and improving dough handling
  • Pharmaceuticals: active ingredient in topical acne treatments, targeting acne-causing bacteria through antimicrobial oxidizing action
  • Personal care: medicated creams and gels at controlled concentrations for antimicrobial function
  • In polymer manufacturing, food treatment and topical pharmaceutical formulations it generates reactive radicals on decomposition.

Good to know: Wetted or diluted with water or plasticizers to reduce explosion risk during handling and transport. Not to be confused with other peroxides; pharmaceutical-grade material must meet USP and Ph. Eur. specifications.

Commercial specifications

  • 70–75% active content (water-wetted)
  • 50% dispersions

Other Names (Synonyms)

Diphenylglyoxal peroxide|Bepio|Benzoyl superoxide|Benzoyl benzenecarboperoxoate|BPO|Dibenzoyl peroxide|Peroxide, dibenzoyl|Lucidol|E928

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What are the physical properties of Benzoyl peroxide?

Melting Point 103-106 °C
Boiling Point 176°F
Density 1.334 g/cm³ @ Temp: 25 °C
Flash Point >230 °F
Appearance Benzoyl peroxide is an odorless, white or colorless crystalline powder.
Color White
Odor odorless
Form powder
Water Solubility Insoluble
Vapor Pressure 0.009Pa at 25℃
Refractive Index 1.5430 (estimate)
Log P 3.2 at 20℃

How is Benzoyl peroxide classified and handled safely? Learn More

Danger
GHS01· Explosive GHS02· Flammable GHS07· Irritant GHS09· Environmental Hazard GHS03· Oxidizing

Hazard Statements

H241 Heating may cause a fire or explosion
H242 Heating may cause a fire
H316 Causes mild skin irritation
H317 May cause an allergic skin reaction

Precautionary Statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P234 Keep only in original packaging.
P235 Keep cool.
P240 Ground and bond container and receiving equipment.

Which trade and regulatory codes apply to Benzoyl peroxide?

HS Code 29163200
UN Number 3108
ADR Class 5.2
WGK (Germany) 2
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