Potassium metabisulfite

CAS Number
16731-55-8
EC Number
240-795-3
E Number
E224

What is Potassium metabisulfite?

Potassium metabisulfite (CAS 16731-55-8), also sold as potassium pyrosulfite and approved as E224, is an inorganic sulfite salt used industrially as a preservative, antioxidant, and reducing agent.

Where is Potassium metabisulfite used?

  • Food: prevents enzymatic browning in dried fruits, potato products, and seafood processing
  • Beverage: sanitizes equipment, inhibits wild yeast, and protects finished products from oxidative spoilage during storage
  • Water treatment: dechlorinates potable water and treats process streams before discharge or further treatment
  • Textile and leather processing: bleaching and reducing agent during fabric preparation
  • It releases sulfur dioxide upon contact with moisture or acids, enabling microbial control and oxidation prevention.

Commercial specifications

  • Purity levels typically range from 97% to 99%
  • Food and pharma grades carry tighter sulfur dioxide content specifications

Other Names (Synonyms)

potassium pyrosulfite|potassium metabisulphite|dipotassium disulphite|dipotassium disulfite|Potassium disulfite|Dipotassium pyrosulfite|Sobisu|Dipotassium metabisulfite|E224

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What are the physical properties of Potassium metabisulfite?

Melting Point 150 °C (decomp)
Density 2.3 g/cm³
Appearance White to slightly yellowish fine cryst. powder
Color White to slightly yellow
Odor Odorless
Form Powder/Solid
Water Solubility Soluble in water. Insoluble in ethanol.
pH 2.5-4.5 (25℃, 0.1M in H2O)

How is Potassium metabisulfite classified and handled safely? Learn More

Danger
GHS05· Corrosive GHS07· Irritant

Hazard Statements

H302 Harmful if swallowed
H315 Causes skin irritation
H318 Causes serious eye damage
H335 May cause respiratory irritation

Precautionary Statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.

Which trade and regulatory codes apply to Potassium metabisulfite?

HS Code 28322000
Storage Class 11 - Combustible Solids
WGK (Germany) 1
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